Find the mass of 250.00 ml of benzene. The density of benzene is 0.8765 g/ml. (Please show how you got this answer)

Wet steam at 1100 kPa expands at constant enthalpy (as in a throttling process) to 101.33 kPa, where its temperature is 105°C. W

nikklg [1K]

Answer:

There are 3 steps of this problem.

Explanation:

Step 1.

Wet steam at 1100 kPa expands at constant enthalpy to 101.33 kPa, where its temperature is 105°C.

Step 2.

Enthalpy of saturated liquid Haq = 781.124 J/g

Enthalpy of saturated vapour Hvap = 2779.7 J/g

Enthalpy of steam at 101.33 kPa and 105°C is H2= 2686.1 J/g

Step 3.

In constant enthalpy process, H1=H2 which means inlet enthalpy is equal to outlet enthalpy

So, H1=H2

H2= (1-x)Haq+XHvap.........1

Putting the values in 1

2686.1(J/g) = {(1-x)x 781.124(J/g)} + {X x 2779.7 (J/g)}

= 781.124 (J/g) - x781.124 (J/g) = x2779.7 (J/g)

1904.976 (J/g) = x1998.576 (J/g)

x = 1904.976 (J/g)/1998.576 (J/g)

x = 0.953

So, the quality of the wet steam is 0.953

7 0

3 years ago

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Hydrogen gas (a potential future fuel) can be formed by the reaction of methane with water according to the following equation:

dem82 [27]

Answer:

The percent yield of the reaction is 62.05 %

Explanation:

Step 1: Data given

Volume of methane = 25.5 L

Pressure of methane = 732 torr

Temperature = 25.0 °C = 298 K

Volume of water vapor = 22.0 L

Pressure of H2O = 704 torr

Temperature = 125 °C

The reaction produces 26.0 L of hydrogen gas measured at STP

Step 2: The balanced equation

CH4(g) + H2O(g) → CO(g) + 3H2(g)

Step 3: Calculate moles methane

p*V = n*R*T

⇒with p = the pressure of methane = 0.963158 atm

⇒with V = the volume of methane = 25.5 L

⇒with n = the moles of methane = TO BE DETERMINED

⇒with R = the gas constant = 0.08206 L*atm/mol*K

⇒with T = the temperature = 298 K

n = (p*V) / (R*T)

n = (0.963158 * 25.5 ) / ( 0.08206 * 298)

n = 1.0044 moles

Step 4: Calculate moles H2O

p*V = n*R*T

⇒with p = the pressure of methane = 0.926316 atm

⇒with V = the volume of methane = 22.0 L

⇒with n = the moles of methane = TO BE DETERMINED

⇒with R = the gas constant = 0.08206 L*atm/mol*K

⇒with T = the temperature = 398 K

n = (p*V) / (R*T)

n = (0.926316 * 22.0) / (0.08206 * 398)

n = 0.624 moles

Step 5: Calculate the limiting reactant

For 1 mol methane we need 1 mol H2O to produce 1 mol CO and 3 moles H2

H2O is the limiting reactant. It will completely be consumed (0.624 moles).

Methane is in excess. There will react 0.624 moles. There will remain 1.0044 - 0.624 moles = 0.3804 moles methane

Step 6: Calculate moles hydrogen gas

For 1 mol methane we need 1 mol H2O to produce 1 mol CO and 3 moles H2

For 0.624 moles H2O we'll have 3*0.624 = 1.872 moles

Step 9: Calculate volume of H2 at STP

1.0 mol at STP has a volume of 22.4 L

1.872 moles has a volume of 1.872 * 22.4 = 41.9 L

Step 10: Calculate the percent yield of the reaction

% yield = (actual yield / theoretical yield) * 100 %

% yield = ( 26.0 L / 41.9 L) *100 %

% yield = 62.05 %

The percent yield of the reaction is 62.05 %

6 0

2 years ago

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At what temperature is the following reaction feasible: HCl(g) + NH3(g) -> NH4Cl(s)?

Nutka1998 [239]

Energy is distributed not just in translational KE, but also in rotation, vibration and also distributed in electronic energy levels (if input great enough, bond breaks).

All four forms of energy are quantised and the quanta ‘gap’ differences increases from trans. KE ==> electronic.

Entropy (S) and energy distribution: The energy is distributed amongst the energy levels in the particles to maximise their entropy.

Entropy is a measure of both the way the particles are arranged AND the ways the quanta of energy can be arranged.

We can apply ΔSθsys/surr/tot ideas to chemical changes to test feasibility of a reaction:

ΔSθtot = ΔSθsys + ΔSθsurr

ΔSθtot must be >=0 for a chemical change to be feasible.

For example: CaCO3(s) ==> CaO(s) + CO2(g)

ΔSθsys = ΣSθproducts – ΣSθreactants

ΔSθsys = SθCaO(s) + SθCO2(g) – SθCaCO3(s)

ΔSθsurr is –ΔHθ/T(K) and ΔH is very endothermic (very +ve),

Now ΔSθsys is approximately constant with temperature and at room temperature the ΔSθsurr term is too negative for ΔSθtot to be plus overall.

But, as the temperature is raised, the ΔSθsurr term becomes less negative and eventually at about 800oCΔSθtot becomes plus overall (and ΔGθ becomes negative), so the decomposition is now chemically, and 'commercially' feasible in a lime kiln.

CaCO3(s) ==> CaO(s) + CO2(g) ΔHθ = +179 kJ mol–1 (very endothermic)

This important industrial reaction for converting limestone (calcium carbonate) to lime (calcium oxide) has to be performed at high temperatures in a specially designed limekiln – which these days, basically consists of a huge rotating angled ceramic lined steel tube in which a mixture of limestone plus coal/coke/oil/gas? is fed in at one end and lime collected at the lower end. The mixture is ignited and excess air blasted through to burn the coal/coke and maintain a high operating temperature.
ΔSθsys = ΣSθproducts – ΣSθreactants
ΔSθsys = SθCaO(s) + SθCO2(g) – SθCaCO3(s) = (40.0) + (214.0) – (92.9) = +161.0 J mol–1 K–1
ΔSθsurr is –ΔHθ/T = –(179000/T)
ΔSθtot = ΔSθsys + ΔSθsurr
ΔSθtot = (+161) + (–179000/T) = 161 – 179000/T
If we then substitute various values of T (in Kelvin) you can calculate when the reaction becomes feasible.
For T = 298K (room temperature)

ΔSθtot = 161 – 179000/298 = –439.7 J mol–1 K–1, no good, negative entropy change

For T = 500K (fairly high temperature for an industrial process)

ΔSθtot = 161 – 179000/500 = –197.0, still no good

For T = 1200K (limekiln temperature)

ΔSθtot = 161 – 179000/1200 = +11.8 J mol–1 K–1, definitely feasible, overall positive entropy change

Now assuming ΔSθsys is approximately constant with temperature change and at room temperature the ΔSθsurr term is too negative for ΔSθtot to be plus overall. But, as the temperature is raised, the ΔSθsurr term becomes less negative and eventually at about 800–900oC ΔSθtot becomes plus overall, so the decomposition is now chemically, and 'commercially' feasible in a lime kiln.
You can approach the problem in another more efficient way by solving the total entropy expression for T at the point when the total entropy change is zero. At this point calcium carbonate, calcium oxide and carbon dioxide are at equilibrium.
ΔSθtot–equilib = 0 = 161 – 179000/T, 179000/T = 161, T = 179000/161 = 1112 K

This means that 1112 K is the minimum temperature to get an economic yield. Well at first sight anyway. In fact because the carbon dioxide is swept away in the flue gases so an equilibrium is never truly attained so limestone continues to decompose even at lower temperatures.

8 0

2 years ago

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The track along which electricity flows is called a: fuse circuit switch

Pavel [41]

It is called a circuit.

4 0

2 years ago

One way to limit iron corrosion is to coat the iron with a metal that:

Lorico [155]

1.)One way to limit iron corrosion is to coat the iron with a metal that:
A.)will never undergo corrosion

3 0

3 years ago

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