Answer:
[EtOH] = 2.2M and Wt% EtOH = 10.1% (w/w)
Explanation:
1. Molarity = moles solute / Volume solution in Liters
=> moles solute = mass solute / formula weight of solute = 9.8g/46g·mol⁻¹ = 0.213mol EtOH
=> volume of solution (assuming density of final solution is 1.0g/ml) ...
volume solution = 9.81gEtOH + 87.5gH₂O = 97.31g solution x 1g/ml = 97.31ml = 0.09731 Liter solution
Concentration (Molarity) = moles/Liters = 0.213mol/0.09731L = 2.2M in EtOH
2. Weight Percent EtOH in solution (assuming density of final solution is 1.0g/ml)
From part 1 => [EtOH] = 2.2M in EtOH = 2.2moles EtOH/1.0L soln
= {(2.2mol)(46g/mol)]/1000g soln] x 100% = 10.1% (w/w) in EtOH.
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Answer:
see explanation below
Explanation:
First to all, this is a redox reaction, and the reaction taking place is the following:
2KMnO4 + 3H2SO4 + 5H2O2 -----> 2MnSO4 + K2SO4 + 8H2O + 5O2
According to this reaction, we can see that the mole ratio between the peroxide and the permangante is 5:2. Therefore, if the titration required 21.3 mL to reach the equivalence point, then, the moles would be:
MhVh = MpVp
h would be the hydrogen peroxide, and p the permanganate.
But like it was stated before, the mole ratio is 5:2 so:
5MhVh = 2MpVp
Replacing moles:
5nh = 2MpVp
Now, we just have to replace the given data:
nh = 2MpVp/5
nh = 2 * 1.68 * 0.0213 / 5
nh = 0.0143 moles
Now to get the mass, we just need the molecular mass of the peroxide:
MM = 2*1 + 2*16 = 34 g/mol
Finally the mass:
m = 0.0143 * 34
m = 0.4862 g
