Explanation:
Solids have definite shape and distinct boundaries as such the intermolecular forces between them is maximum
Answer:
Part 1: - 1.091 x 10⁴ J/mol.
Part 2: - 1.137 x 10⁴ J/mol.
Explanation:
Part 1: At standard conditions:
At standard conditions Kp= 81.9.
∵ ΔGrxn = -RTlnKp
∴ ΔGrxn = - (8.314 J/mol.K)(298.0 K)(ln(81.9)) = - 1.091 x 10⁴ J/mol.
Part 2: PICl = 2.63 atm; PI₂ = 0.324 atm; PCl₂ = 0.217 atm.
For the reaction:
I₂(g) + Cl₂(g) ⇌ 2ICl(g).
Kp = (PICl)²/(PI₂)(PCl₂) = (2.63 atm)²/(0.324 atm)(0.217 atm) = 98.38.
∵ ΔGrxn = -RTlnKp
∴ ΔGrxn = - (8.314 J/mol.K)(298.0 K)(ln(98.38)) = - 1.137 x 10⁴ J/mol.
Answer:
the equilibrium concentration of [PCl₅] is 3.64*10⁻³ M
Explanation:
for the reaction
PCl₅(g) → PCl₃(g) + Cl₂(g)
where
Kc= [PCl₃]*[Cl₂]/[PCl₅] = 2.0*10¹ M = 20 M
and [A] denote concentrations of A
if initially the mixture is pure PCl₅ , then it will dissociate according to the reaction and since always one mole of PCl₃(g) is generated with one mole of Cl₂(g) , the total number of moles of both at the end is the same → they have the same concentration → [PCl₃(g)] = [Cl₂]=0.27 M
therefore
Kc= [PCl₃]*[Cl₂]/[PCl₅] = 0.27 M* 0.27 M /[PCl₅] = 20 M
[PCl₅] = 0.27 M* 0.27 M / 20 M = 3.64*10⁻³ M
[PCl₅] = 3.64*10⁻³ M
the equilibrium concentration of [PCl₅] is 3.64*10⁻³ M
I believe it is “Conduction” im not 100% sure tho, I haven’t done this since the 7th grade.
