Answer:
the Molar heat of Combustion of diphenylacetylene
= 
Explanation:
Given that:
mass of diphenylacetylene
= 0.5297 g
Molar Mass of diphenylacetylene
= 178.21 g/mol
Then number of moles of diphenylacetylene
= 
= 
= 0.002972 mol
By applying the law of calorimeter;
Heat liberated by 0.002972 mole of diphenylacetylene
= Heat absorbed by
+ Heat absorbed by the calorimeter
Heat liberated by 0.002972 mole of diphenylacetylene
= msΔT + cΔT
= 1369 g × 4.184 J g⁻¹°C⁻¹ × (26.05 - 22.95)°C + 916.9 J/°C (26.05 - 22.95)°C
= 17756.48 J + 2842.39 J
= 20598.87 J
Heat liberated by 0.002972 mole of diphenylacetylene
= 20598.87 J
Heat liberated by 1 mole of diphenylacetylene
will be = 
= 6930979.139 J/mol
= 6930.98 kJ/mol
Since heat is liberated ; Then, the Molar heat of Combustion of diphenylacetylene
= 
Here we assume that disintegration has occur so the normal t½ formular will not be used
mathematically we..⅛×5600 =700
therefore it is about 700years option A
Answer:224
Explanation:
We should answer it with Stoichiometry
We say: 20 g H2× (1 mol/ 2g)× ( 22.4 lit/ 1 mol) = 224
Means: we have 20 grams and every 2g H2, equals to 1 mol of it and every 1 mol of H2, equals to 22.4 lit( because of STP)
hope you got this:)
Alkenes on reacting with ozone results in the formation of ozonide which undergo reductive cleavage in presence of dimethyl sulfide to form carbonyl compounds (aldehyde or ketone). Whereas in presence of hydrogen peroxide it undergoes oxidative cleavage to form carboxylic acids or ketones.
Since, A alkene yields 4-heptanone only on treatment with ozone and DMS thus, it implies that both the chains on the side of the double-bond are similar the product is 4-heptanone that means the double bond is present between the chains at the 4th carbon. Therefore the structure of compound A is 4,5-dipropyloct-4-ene.
The reaction is as shown in the image.
The reaction of A with m-CPBA (meta-perchlorobenzoic acid) followed by aqueous acid
is shown in the image.
m-CPBA (meta-perchlorobenzoic acid) is a peracid and forms epoxides on reacting with alkenes.