Nitrogen (N2) and hydrogen (H2) gases react to form ammonia, which requires -99.4 J/K of standard entropy (ΔS°).
What is standard entropy?
The difference between the total standard entropies of the reaction mixture and the summation of the standard entropies of the outputs is the standard entropy change. Each entropy in the balanced equation needs to be compounded by its coefficient, as shown by the letter "n."
Calculation:
Balancing the given reaction following-
1/2 N₂(g) + 3/2 H₂ (g)→ NH₃ (g)
ΔS° = [1 mol x S° (NH₃)g] - [1/2 mol x S° (N₂)g] - [3/2 mol x S°(H₂)g]
Here S° = standard entropy of the system
Insert into the aforementioned equation all the typical entropy values found in the literature:
ΔS° = [1 mol x 192.45 J/mol.K] - [1/2 mol x 191.61 J/mol.K] - [3/2 mol x 130.684 J/mol.K]
⇒ΔS° = - 99.4 J/K
Therefore, the standard entropy, ΔS° is -99.4 J/K.
Learn more about standard entropy here:
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Answer:
Volume of container = 0.0012 m³ or 1.2 L or 1200 ml
Explanation:
Volume of butane = 5.0 ml
density = 0.60 g/ml
Room temperature (T) = 293.15 K
Normal pressure (P) = 1 atm = 101,325 pa
Ideal gas constant (R) = 8.3145 J/mole.K)
volume of container V = ?
Solution
To find out the volume of container we use ideal gas equation
PV = nRT
P = pressure
V = volume
n = number of moles
R = gas constant
T = temperature
First we find out number of moles
<em>As Mass = density × volume</em>
mass of butane = 0.60 g/ml ×5.0 ml
mass of butane = 3 g
now find out number of moles (n)
n = mass / molar mass
n = 3 g / 58.12 g/mol
n = 0.05 mol
Now put all values in ideal gas equation
<em>PV = nRt</em>
<em>V = nRT/P</em>
V = (0.05 mol × 8.3145 J/mol.K × 293.15 K) ÷ 101,325 pa
V = 121.87 ÷ 101,325 pa
V = 0.0012 m³ OR 1.2 L OR 1200 ml
Answer:
1223.38 mmHg
Explanation:
Using ideal gas equation as:
where,
P is the pressure
V is the volume
n is the number of moles
T is the temperature
R is Gas constant having value = 
Also,
Moles = mass (m) / Molar mass (M)
Density (d) = Mass (m) / Volume (V)
So, the ideal gas equation can be written as:
Given that:-
d = 1.80 g/L
Temperature = 32 °C
The conversion of T( °C) to T(K) is shown below:
T(K) = T( °C) + 273.15
So,
T = (32 + 273.15) K = 305.15 K
Molar mass of nitrogen gas = 28 g/mol
Applying the equation as:
P × 28 g/mol = 1.80 g/L × 62.3637 L.mmHg/K.mol × 305.15 K
⇒P = 1223.38 mmHg
<u>1223.38 mmHg must be the pressure of the nitrogen gas.</u>
Answer : The molecular weight of a substance is 157.3 g/mol
Explanation :
As we are given that 7 % by weight that means 7 grams of solute present in 100 grams of solution.
Mass of solute = 7 g
Mass of solution = 100 g
Mass of solvent = 100 - 7 = 93 g
Formula used :
where,
= change in freezing point
= temperature of pure water = 
= temperature of solution = 
= freezing point constant of water = 
m = molality
Now put all the given values in this formula, we get
Therefore, the molecular weight of a substance is 157.3 g/mol
