Need help in AP Chemistry

Be sure to answer all parts. Consider the reaction A + B → Products From the following data obtained at a certain temperature, d

worty [1.4K]

Answer : The order of reaction with respect to A is, first order reaction.

The order of reaction with respect to B is, zero order reaction.

The overall order of reaction is, first order reaction.

Explanation :

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

$A+B\rightarrow Products$

Rate law expression for the reaction:

$\text{Rate}=k[A]^a[B]^b$

where,

a = order with respect to A

b = order with respect to B

Expression for rate law for first observation:

$3.20\times 10^{-1}=k(1.50)^a(1.50)^b$ ....(1)

Expression for rate law for second observation:

$3.20\times 10^{-1}=k(1.50)^a(2.50)^b$ ....(2)

Expression for rate law for third observation:

$6.40\times 10^{-1}=k(3.00)^a(1.50)^b$ ....(3)

Dividing 1 from 2, we get:

$\frac{3.20\times 10^{-1}}{3.20\times 10^{-1}}=\frac{k(1.50)^a(2.50)^b}{k(1.50)^a(1.50)^b}\\\\1=1.66^b\\b=0$

Dividing 1 from 3, we get:

$\frac{6.40\times 10^{-1}}{3.20\times 10^{-1}}=\frac{k(3.00)^a(1.50)^b}{k(1.50)^a(1.50)^b}\\\\2=2^a\\a=1$

Thus, the rate law becomes:

$\text{Rate}=k[A]^1[B]^0$

$\text{Rate}=k[A]$

Thus,

The order of reaction with respect to A is, first order reaction.

The order of reaction with respect to B is, zero order reaction.

The overall order of reaction is, first order reaction.

7 0

3 years ago

Why males on average have VO2max than females?

katrin [286]

The average sedentary male will achieve a VO2 max of approximately 35 to 40 mL/Kg/min. And the average sedentary female will score a VO2 max of between 27 an 30 mL/Kg/min.

6 0

3 years ago

What type of compound can be<br> described by the following image?

uranmaximum [27]

Answer:

Covalent molecule

Explanation:

i just had got the answer right

5 0

2 years ago

In the gas-phase reaction 2A + B <-> 3C + 2D, it was found that, when 1.00 mol A, 2.00 mol B, and 1.00 mol D were mixed an

Dvinal [7]

Answer:

Mole fraction: A = 8.70%, B = 37.00%, C = 19.60%, D = 34.80%

K = 6.86

Standard reaction free energy change: -4.77 kJ/mol

Explanation:

Let's do an equilibrium chart for the reaction:

2A + B ⇄ 3C + 2D

1.00 2.00 0 1.00 Initial

-2x -x +3x +2x Reacts (stoichiometry is 2:1:3:2)

1-2x 2-x 3x 1+2x Equilibrium

3x = 0.9

x = 0.3 mol

Thus, the number of moles of each one at the equilibrium is:

A = 1 - 2*0.3 = 0.4 mol

B = 2 - 0.3 = 1.7 mol

C = 0.9 mol

D = 1 + 2*0.3 = 1.6 mol

The molar fraction is the mol of the component divided by the total number of moles (0.4 + 1.7 + 0.9 + 1.6 = 4.6 mol):

A = 0.4/4.6 = 0.087 = 8.70%

B = 1.7/4.6 = 0.37 = 37.00%

C = 0.9/4.6 = 0.196 = 19.60%

D = 1.6/4.6 = 0.348 = 34.80%

The equilibrium constant is the multiplication of the concentration of the products elevated by their coefficients, divided by the multiplication of the concentration of the reactants elevated by their coefficients. Because the volume remains constant, we can use the number of moles:

K = (nC³*nD²)/(nA²*nB)

K = (0.9³ * 1.6²)/(0.4² * 1.7)

K = 6.86

The standard reaction free energy change can be calculated by:

ΔG° = -RTlnK

Where R is the gas constant (8.314 J/mol.K), and T is the temperature (25°C = 298 K)

ΔG° = -8.314*298*ln6.86

ΔG° = -4772.8 J/mol

ΔG° = -4.77 kJ/mol

5 0

4 years ago

What is this equation balanced?

Brums [2.3K]

This equation is impossible. NaSO4 is non-existent. Did you mean Na2SO4?

4 0

3 years ago