propose a mechanism (curved arrows) for the following sn1 reaction. based on the mechanism, do you think that the products will
1 answer:
In SN1 reaction, the products will be formed as a racemic mixture.
<h3>What is racemic mixture?</h3>Racemic mixture also called racemate, a mixture of equal quantities of two enantiomers, or substances that have dissymmetric molecular structures that are mirror images of one another.
<h3>What is SN1 reaction?</h3>SN1 reaction corresponds to unimolecular nucleophilic substitution reaction. The order of reaction is one. The hydrolysis of tert-butyl bromide with aqueous NaOH solution is an example of SN1 reaction.
<h3>Why in SN1 reaction products will be formed as a racemic mixture?</h3>The carbocation and its substituents are all in the same plane, meaning that the nucleophile can attack from either side. As a result, both enantiomers are formed in an the SN1 reaction, leading to a racemic mixture of both enantiomers.
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Answer:
Explanation:
From the information given:
Mass of carbon tetrachloride = 5 kg
Pressure = 1 bar
The given density for carbon tetrachloride = 1590 kg/m³
The specific heat of carbon tetrachloride = 0.84 kJ/kg K
From the composition, the initial volume of carbon tetrachloride will be:
= 0.0031 m³
Suppose is independent of temperature while pressure is constant;
Then:
The change in volume can be expressed as:
However; the workdone = -PdV
W = - 7.6 J
The heat energy Q = Δ h
Q = 84 kJ
The internal energy is calculated by using the 1st law of thermodynamics; which can be expressed as;
ΔU = ΔQ + W
ΔU = 84 kJ + ( -7.6 × 10⁻³ kJ)
ΔU = 83.992 kJ