Answer:
Indirect. I don't think it's cycling and it's not direct or constant
Given information : H = -92 KJ/mol and S = -0.199 KJ/(mol.K)
At equilibrium G = 0
We have to find the Temperature at which reaction would be spontaneous.
For spontaneous reaction : 
For non-spontaneous reaction : 
We can find the temperature using the formula for Gibbs free energy which is:

Where, G = Gibbs free energy ,
H = Enthalpy
S = Entropy
T = Temperature
By plugging the value of G , H and S in the above formula we can find 'T'

Since reaction should be spontaneous that means
should be negative , so the above formula can be written as :

On rearranging the above formula we get :




For the reaction to be spontaneous , T should be less than 462.3 K, so out of given option , C is correct which is 400 K.
Answer: n∗R=22+273.15/4.2∗5n
P2=n∗R∗T2/V2=n∗R∗33.6+273.15/10
Explanation: