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crimeas [40]
3 years ago
14

A reaction has a standard free-energy change of -14.50 kJ mol(-3.466 kcal mol). Calculate the equilibrium constant for the react

ion at 25 °C. 5.85 K
Chemistry
1 answer:
den301095 [7]3 years ago
5 0

Answer:  The equilibrium constant for the reaction at 25 °C is 346.7

Explanation:

Formula used :

\Delta G^o=-2.303\times RT\times \log K_c

where,

\Delta G^o = standard Gibb's free energy change = -14.50kJ/mol =14500 J/mol

R = universal gas constant = 8.314 J/K/mole

T = temperature = 25^0C= (25+273)K=298 K

K_c = equilibrium constant = ?

Putting in the values we get:

-14500=-2.303\times 8.314\times 298\times \log K_c

\log K_c=2.54

K_c=antilog(2.54)=346.7

The equilibrium constant for the reaction at 25 °C is 346.7

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⦁ Find the concentration of H+, OH-, PH and POH of 0.03 M of magnesium hydroxide which ionizes to the extent of only 1 /3 in aqu
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Answer:

pH=12.3\\\\pOH=1.7\\

[H^+]=5x10^{-13}M

[OH^-]=0.02M

Explanation:

Hello there!

In this case, according to the given ionization of magnesium hydroxide, it is possible for us to set up the following reaction:

Mg(OH)_2(s)\rightleftharpoons Mg^{2+}(aq)+2OH^-(aq)

Thus, since the ionization occurs at an extent of 1/3, we can set  up the following relationship:

\frac{1}{3} =\frac{x}{[Mg(OH)_2]}

Thus, x for this problem is:

x=\frac{[Mg(OH)_2]}{3}=\frac{0.03M}{3}\\\\x=  0.01M

Now, according to an ICE table, we have that:

[OH^-]=2x=2*0.01M=0.02M

Therefore, we can calculate the H^+, pH and pOH now:

[H^+]=\frac{1x10^{-14}}{0.02}=5x10^{-13}M

pH=-log(5x10^{-13})=12.3\\\\pOH=14-pH=14-12.3=1.7

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Compound X has a molar mass of 316.25 g*mol^-1 and the following composition:
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Answer:

Compound X has a molar mass of 316.25 g*mol^-1 and the following composition:

element & mass %

phosphorus & 39.18%

sulfur & 60.82%

Write the molecular formula of X.

Explanation:

The given molecule of phosphorus and sulfur has molar mass --- 316.25 g.

Empirical formula calculation:                      

element:              phosphorus                       sulfur

co9mposition:      39.185%                            60.82%

divide with

atomic mass:          39.185/31.0 g/mol           60.82/32.0g/mol

                              =1.26mol                           1.90mol

smallest mole ratio:   1.26mol/1.26mol =1      1.90mol/1.26 mol =1.50

multiply with 2:          2                                         3

Hence, the empirical formula is:

P2S3.

Mass of empirical formula is:

158.0g/mol

Given, molecule has molar mass --- 316.25 g/mol

Hence, the ratio is:

316.25g/mol/158.0 =2

Hence, the molecular formula of the compound is :

2 x (P2S3)

=P_4S_6

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