Answer:
A. 0.143 M
B. 0.0523 M
Explanation:
A.
Let's consider the neutralization reaction between potassium hydroxide and potassium hydrogen phthalate (KHP).
KOH + KHC₈H₄O₄ → H₂O + K₂C₈H₄O₄
The molar mass of KHP is 204.22 g/mol. The moles corresponding to 1.08 g are:
1.08 g × (1 mol/204.22 g) = 5.28 × 10⁻³ mol
The molar ratio of KOH to KHC₈H₄O₄ is 1:1. The reacting moles of KOH are 5.28 × 10⁻³ moles.
5.28 × 10⁻³ moles of KOH occupy a volume of 36.8 mL. The molarity of the KOH solution is:
M = 5.28 × 10⁻³ mol / 0.0368 L = 0.143 M
B.
Let's consider the neutralization of potassium hydroxide and perchloric acid.
KOH + HClO₄ → KClO₄ + H₂O
When the molar ratio of acid (A) to base (B) is 1:1, we can use the following expression.
INGREDIENTS:SUGAR, INVERT SUGAR, CORN SYRUP, MODIFIED CORN STARCH, CITRIC ACID, WHITE MINERAL OIL, NATURAL AND ARTIFICIAL FLAVOR, RED 40, AND CARNABUBA WAX.
Answer:
The reaction is not spontaneous in the forward direction, but in the reverse direction.
Explanation:
<u>Step 1: </u>Data given
H2(g) + I2(g) ⇌ 2HI(g) ΔG° = 2.60 kJ/mol
Temperature = 25°C = 25+273 = 298 Kelvin
The initial pressures are:
pH2 = 3.10 atm
pI2 = 1.5 atm
pHI 1.75 atm
<u>Step 2</u>: Calculate ΔG
ΔG = ΔG° + RTln Q
with ΔG° = 2.60 kJ/mol
with R = 8.3145 J/K*mol
with T = 298 Kelvin
Q = the reaction quotient → has the same expression as equilibrium constant → in this case Kp = [p(HI)]²/ [p(H2)] [p(I2)]
with pH2 = 3.10 atm
pI2 = 1.5 atm
pHI 1.75 atm
Q = (3.10²)/(1.5*1.75)
Q = 3.661
ΔG = ΔG° + RTln Q
ΔG = 2600 J/mol + 8.3145 J/K*mol * 298 K * ln(3.661)
ΔG =5815.43 J/mol = 5.815 kJ/mol
To be spontaneous, ΔG should be <0.
ΔG >>0 so the reaction is not spontaneous in the forward direction, but in the reverse direction.
Explanation:
(1) The nucleus is positive and the electron cloud is positive.
(2) The nucleus is positive and the electron cloud is negative.
(3) The nucleus is negative and the electron cloud is positive.
(4) The nucleus is negative and the electron cloud is negative
