Question

Who made himself head of the English church in 1533 after being excommunicated by the Pope

Answer 1

The answer is King Henry VIII. hope that helps. 

Answer 2

The title was created for King Henry VIII, who was responsible for the English Christian (protestant) church breaking away from the authority of the Roman Catholic Church after the Pope excommunicated Henry in 1533 over his divorce from Catherine of Aragon. 
hope this helped:)