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Alexxandr [17]
3 years ago
8

Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constan

t (g) (g) (g) (g) (g) (g) Suppose also ≫. That is, the first step is much faster than the second.
Write the balanced chemical equation for the overall chemical reaction:
Write the experimentally-observable rate law for the overall chemical reaction.

Note: your answer should not contain the concentrations of any intermediates.
Chemistry
1 answer:
Oksana_A [137]3 years ago
8 0

Answer:

Koverall [NO]^2 [Br2]

Balanced chemical reaction equation;

2NO + Br2 ⇄2NOBr

Explanation:

Consider the first step in the reaction;

NO(g) + Br2(g) ⇄ NOBr2(g) fast

The second step is the slower rate determining step

NOBr2(g) + NO(g) ⇄ 2NOBr(g)

Given that k1= [NOBr2]/[NO] [Br2]

k2= [NOBr2] [NO]

The concentration of the intermediate is now;

[NOBr2]= k1[NO][Br2]

It then follows that overall rate of reaction is

Rate= k1k2[NO]^2 [Br2]

Since k1k2=Koverall

Rate= Koverall [NO]^2 [Br2]

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Given the following two quantities: 0.50 mol of CH4 and 1.0 mol of HCl,
Vinil7 [7]

Answer:

(a) HCl

(b) HCl

(c) HCl

(d) HCl

Explanation:

<em>Given: </em>0.50 mol of CH₄ and 1.0 mol of HCl

Using stoichiometry we can calculate the answers to parts a, b, c, and d.

<h3>Part (a) </h3>

# of moles × Avogadro's number = # of atoms or molecules

Avogadro's number: 6.02 * 10²³

  • \displaystyle 0.50\ \text{mol CH}_4 \cdot \frac{6.02\cdot 10^2^3 \ \text{atoms CH}_4}{1 \ \text{mol CH}_4} = 3.01 \cdot 10^2^3 \ \text{atoms CH}_4
  • \displaystyle 1.0\ \text{mol HCl} \cdot \frac{6.02\cdot 10^2^3 \ \text{atoms HCl}}{1 \ \text{mol HCl}} = 6.02 \cdot 10^2^3 \ \text{atoms HCl}

HCl has more atoms than CH₄.

<h3>Part (b) </h3>

This is calculated the same way as Part (a); HCl has more molecules than CH₄.

<h3>Part (c) </h3>

Molar mass of CH₄ = 16.04 g/mol

Molar mass of HCl = 36.458 g/mol

  • \displaystyle 0.50\ \text{mol CH}_4 \cdot \frac{16.04 \ \text{g CH}_4}{1 \ \text{mol CH}_4} = 8.02 \ \text{g CH}_4
  • \displaystyle 1.0\ \text{mol HCl} \cdot \frac{36.458 \ \text{g HCl}}{1 \ \text{mol HCl}} = 36.458 \ \text{g HCl}

HCl has a greater mass than CH₄.

<h3>Part (d)</h3>

Assuming STP:

Molar volume of any gas at STP is 22.4 L/mol.

  • \displaystyle 0.50\ \text{mol CH}_4 \cdot \frac{22.4 \ \text{L CH}_4}{1 \ \text{mol CH}_4} = 11.2 \ \text{L CH}_4
  • \displaystyle 1.0\ \text{mol HCl} \cdot \frac{22.4 \ \text{L HCl}}{1 \ \text{mol HCl}} = 22.4 \ \text{L HCl}

HCl has a greater volume than CH₄.

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A balloon contains 0.950 mol of nitrogen gas and has a volume of 25.5 L. How many grams of N2 should be released from the balloo
kirill [66]
Answer:
Mass released = 8.6 g
Explanation:
Given data:
Initial number of moles nitrogen= 0.950 mol
Initial volume = 25.5 L
Final mass of nitrogen released = ?
Final volume = 17.3 L
Solution:
Formula:
V₁/n₁ = V₂/n₂
25.5 L / 0.950 mol = 17.3 L/n₂
n₂ = 17.3 L× 0.950 mol/25.5 L
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Mass = 0.950 mol × 28 g/mol
Mass = 26.6 g
Final mass of nitrogen:
Mass = number of moles × molar mass
Mass = 0.644 mol × 28 g/mol
Mass = 18.0 g
Mass released = initial mass - final mass
Mass released = 26.6 g - 18.0 g
Mass released = 8.6 g
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