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Alexxandr [17]
3 years ago
8

Suppose the reaction between nitric oxide and bromine proceeds by the following mechanism: step elementary reaction rate constan

t (g) (g) (g) (g) (g) (g) Suppose also ≫. That is, the first step is much faster than the second.
Write the balanced chemical equation for the overall chemical reaction:
Write the experimentally-observable rate law for the overall chemical reaction.

Note: your answer should not contain the concentrations of any intermediates.
Chemistry
1 answer:
Oksana_A [137]3 years ago
8 0

Answer:

Koverall [NO]^2 [Br2]

Balanced chemical reaction equation;

2NO + Br2 ⇄2NOBr

Explanation:

Consider the first step in the reaction;

NO(g) + Br2(g) ⇄ NOBr2(g) fast

The second step is the slower rate determining step

NOBr2(g) + NO(g) ⇄ 2NOBr(g)

Given that k1= [NOBr2]/[NO] [Br2]

k2= [NOBr2] [NO]

The concentration of the intermediate is now;

[NOBr2]= k1[NO][Br2]

It then follows that overall rate of reaction is

Rate= k1k2[NO]^2 [Br2]

Since k1k2=Koverall

Rate= Koverall [NO]^2 [Br2]

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Answer:

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Explanation:

The 1HNMR is the acronym for Proton nuclear magnetic resonance and it is used in chemistry or Chemical laboratory for the analysis and identification of compounds.

In order to be able to answer the question accurately you have to have the tables containing all the values for chemical shift. The Chemical shift is measured in ppm and it occur due to Resonance frequency variation.

From the table, a singlet at 1.15 ppm (9H) is - C(CH3)3.

A singlet at d 0.9 ppm (1H) shows the presence of a secondary amine group, that is -R2NH group.

A triplet at 1.10 ppm (3H) shows that we have;

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A quartet at 2.6 ppm (2H) shows that we have;

-CH2 - CH3.

Therefore, joining all together we have;

CH3 - CH2 - NH - C(CH3)3.

Kindly check attached file for the picture of the structure.

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