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aleksley [76]
3 years ago
9

The radioactive substance cesium-137 has a half-life of 30 years. The amount At (in grams) of a sample of cesium-137 remaining a

fter t years is given by the following exponential function.
At(t)=458(1/2)^(t/30)
Find the amount of the sample remaining after 20 years and after 50 years. Round your answers to the nearest gram as necessary.
Chemistry
1 answer:
stealth61 [152]3 years ago
6 0

<u>Answer:</u> The amount of sample left after 20 years is 288.522 g and after 50 years is 144.26 g

<u>Explanation:</u>

We are given a function that calculates the amount of sample remaining after 't' years, which is:

A_t(t)=458\times (\frac{1}{2})^{\frac{t}{30}

  • <u>For t = 20 years</u>

Putting values in above equation:

A_t(t)=458\times (\frac{1}{2})^{\frac{20}{30}

A_t(t)=288.522g

Hence, the amount of sample left after 20 years is 288.522 g

  • <u>For t = 50 years</u>

Putting values in above equation:

A_t(t)=458\times (\frac{1}{2})^{\frac{50}{30}

A_t(t)=144.26g

Hence, the amount of sample left after 50 years is 144.26 g

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Answer:

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2 years ago
Consider the titration of 1L of 0.36 M NH3 (Kb=1.8x10−5) with 0.74 M HCl. What is the pH at the equivalence point of the titrati
worty [1.4K]

Answer:

C

Explanation:

The question asks to calculate the pH at equivalence point of the titration between ammonia and hydrochloric acid

Firstly, we write the equation of reaction between ammonia and hydrochloric acid.

NH3(aq)+HCl(aq)→NH4Cl(aq)

Ionically:

HCl + NH3 ---> NH4  +  Cl-

Firstly, we calculate the number of moles of  the ammonia  as follows:

from c = n/v and thus, n = cv = 0.36 × 1 = 0.36 moles

At the equivalence point, there is equal number of moles of ammonia and HCl.

Hence, volume of HCl = number of moles/molarity of HCl = 0.36/0.74 = 0.486L

Hence, the total volume of solution will be 1 + 0.486 = 1.486L

Now, we calculate the concentration of the ammonium ions = 0.36/1.486 = 0.242M

An ICE TABLE IS USED TO FIND THE CONCENTRATION OF THE HYDROXONIUM ION(H3O+). ICE STANDS FOR INITIAL, CHANGE AND EQUILIBRIUM.

                 NH4+      H2O     ⇄  NH3        H3O+

I                0.242                           0             0

C                 -X                              +x              +X

E             0.242-X                          X              X

Since the question provides us with the base dissociation constant value K b, we can calculate the acid dissociation constant value Ka

To find this, we use the mathematical equation below

K a ⋅ K b    = K w

 

, where  K w- the self-ionization constant of water, equal to  

10 ^-14  at room temperature

This means that you have

K a = K w.K b   = 10 ^− 14 /1.8 * 10^-5 =  5.56 * 10^-10

Ka = [NH3][H3O+]/[NH4+]

= x * x/(0.242-x)

Since the value of Ka is small, we can say that 0.242-x ≈  0.242

Hence, K a = x^2/0.242 = 5.56 * 10^-10

x^2 = 0.242 * 5.56 * 10^-10 = 1.35 * 10^-10

x = 0.00001161895

[H3O+] = 0.00001161895

pH = -log[H3O+]

pH = -log[0.00001161895 ] = 4.94

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Answer:

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(B) 0.237 M

Explanation:

(A) The reaction between potassium hydrogen phthalate and barium hydroxide is:

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Where A⁻ is the respective anion of the monoprotic acid (KC₈H₄O₄⁻).

We <u>convert mass of phthalate to moles</u>, using its molar mass:

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Now we <u>convert mmol of HA to mmol of Ba(OH)₂</u>:

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Finally we calculate the molarity of the Ba(OH)₂ solution:

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(B) The reaction between Ba(OH)₂ and HCl is:

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