Answer: a) The concentration after 8.8min is 0.17 M
b) Time taken for the concentration of cyclopropane to decrease from 0.25M to 0.15M is 687 seconds.
Explanation:
Expression for rate law for first order kinetics is given by:
where,
k = rate constant
t = age of sample
a = let initial amount of the reactant
a - x = amount left after decay process
a) concentration after 8.8 min:
b) for concentration to decrease from 0.25M to 0.15M
Answer:
Explanation:
A neutral titanium atom will have 22 electrons. Therefore, its electron configuration will be 1s2 2s2 2p6 3s2 3p6 4s2 3d2.
Answer:
p-fluoronitrobenzene and sodium phenoxide is more appropriate
Explanation:
An ipso substitution is required to form p-nitrophenyl phenyl ether.
For this ipso substitution, an alkoxide anion needs to attack as a nucleophile at the carbon atom attached to fluorine atom and thereby substitute that F atom.
p-nitrophenoxide is an weak nucleophile as compared to phenoxide due to presence of electron withdrawing resonating effect of nitro group at para position.
p-fluoronitrobenzene is a good choice for nucleophilic attack by alkoxide anion as compared to fluorobenzene due to higher positive charge density at carbon atom directly attached to F atom. Higher positive charge density arises due to presence of electron withdrawing resonating effect og nitro group at para position.
So, p-fluoronitrobenzene and sodium phenoxide is more appropriate
