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stira [4]
3 years ago
11

The enthalpy change for converting 10.0 g of ice at -25.0 °C to water at 90.0 °C is __________ kJ. The specific heats of ice, wa

ter, and steam are 2.09 J/g-K, 4.18 J/g-K, and 1.84 J/g-K, respectively. For H2O, = 6.01 kJ/mol, and = 40.67 kJ/mol.
Chemistry
1 answer:
Nina [5.8K]3 years ago
6 0
AH1 = m * c1 * AT1 calculate this for ice (-25C to 0C) AH2 = AHfus(1 mole)=6.01 kJ = 6010 J AH3 = m *c3 * AT3 calculat this for water (0C to 100C) AH4 = AHvap(1mole)=40.67 kJ = 40670 J AH5= m * c5 * AT5 calculate this for steam (100C to 125C) 
Sum ---- AH1+AH2+AH3+AH4+AH5 
Data m=18g (1mole water) 
c1=specific heat ice= 2.09 J/g K c3=specific heat water= 4.18 J/g K c5=specific heat steam= 1.84 J/g K 
AT = (Tend - Tinitial) as this is a difference between temperatures it doesn't matter the units Celsius or Kelvin. Kelvin (K)=Celsius (C)+273.15 
AT1 = 0C - (-25C)= 25C= 273.15K - 248.15K= 25K AT3= 100C - 0C = 100C= 100K AT5= 125C - 100C= 25C=25K
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Answer:

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  • percent yield of H₂SO₄ = 94 %  

Explanation:

Data Given:

volume of SO₂ = 48.6 L

mass of H₂SO₄ = 200 g

balance equation = ?

theoretical yield = ?

percent yield = ?

Solution:

Part 1:

first we have to write a balance equation for the reaction

SO₂ gas react with water (H₂O) and excess oxygen

The balanced equation is as under

                       2SO₂ +  O₂ + 2H₂O  -----------> 2H₂SO₄

Part 2:

Now we have to find theoretical yield

First look at the balance reaction

                        2SO₂ +  O₂ + 2H₂O  -----------> 2H₂SO₄

                        2 mol                                         2 mol

2 moles of SO₂ give gives 2 moles of H₂SO₄

Now calculate volume of 2 moles of SO₂ and mass of 2 moles of H₂SO₄

volume of 2 moles of SO₂

Formula used

                 volume of gas = no. of moles x molar volume . . . . . . (1)

molar volume of SO₂= 22.4 L/mol

Put values in above formula (1)

                 volume of gas = 2 mol x 22.4 L/mol

                 volume of gas = 44.8 L

volume of 2 mole of SO₂ = 44.8 L

Now,

Find mass of 2 mole H₂SO₄

Formula Used

            mass in grams = no. of moles x molar mass . . . . . . . (2)

molar mass of H₂SO₄ = 2 (1) + 32 + 4(16)

molar mass of H₂SO₄ = 98 g/mol

put values in equation 2

        mass in grams = 2 mol x 98 g/mol

        mass in grams = 196 g

mass of 2 mole of H₂SO₄ = 196 g

** So,

Now we come to know that

44.8 L of SO₂ gives 196 g of H₂SO₄ then how many grams of the H₂SO₄ will be produced by 48.6 L of SO₂

Apply unity Formula

               44.8 L of SO₂ ≅ 196 g of H₂SO₄

               48.6 L of SO₂ ≅ X g of H₂SO₄

Do cross multiplication

                g of H₂SO₄  = 196 g x 48.6 L / 44.8 L

                g of H₂SO₄  =  213 g

So that is why the theoretical yield of H₂SO₄ is 213 g

Theoretical yield of H₂SO₄ = 213 g

Part 3

Calculate Percent Yield:

Formula used for this purpose:

             percent yield = actual yield /theoretical yield x 100 %

Put value in the above formula

           percent yield = 200 g/ 213 g x 100 %

          percent yield = 94 %    

So percent yield of H₂SO₄ = 94 %    

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