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pishuonlain [190]
3 years ago
7

Identify the appropriate reagent (A-H) you would use to accomplish the given transformation. A. MeONa B. H2, Pt C. t-BuOK D. 1)

Hg(OAc)2, H2O; 2) NaBH4 E. HBr F. HBr, ROOR G. HCl H. 1) BH3-THF; 2) H2O2, NaOH

Chemistry
1 answer:
Aleksandr-060686 [28]3 years ago
3 0

(See full question in attachment)

Answer:

A. MeONa

Explanation:

One of the methods to prepare alkenes are eliminations.

The E2 reaction (for elimination, bimolecular) occurs when an alkyl halide  is treated with a strong base, such as hydroxide ion or alkoxide ion (RO⁻).

It is the most common mechanism that occurs for an elimination.

The methoxide ion is a strong base that will attack the neighboring hydrogen of the halide ion and will start removing H⁺ at the same time that the double bond of the alkene begins to form and the group X begins to leave.

Then, the neutral alkene is produced  when the  C – H link and X group has left  with the electron pair of the bond  C – X (mechanism in attachment).

Therefore, MeONa would be an appropiate reagent.

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The process involved in this problem are :

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Q=[m\times c_{p,l}\times (T_{final}-T_{initial})]+[m\times \Delta H_{fusion}]+[m\times c_{p,s}\times (T_{final}-T_{initial})]

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c_{p,l} = specific heat of liquid benzene = 1.73J/g^oC=1.73J/g.K

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Q=[94.4g\times 1.73J/g.K\times (279-322)K]+[94.4g\times -125.6J/g]+[94.4g\times 1.51J/g.K\times (205-279)K]

Q=-29427.312J=-29.4kJ

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