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Paraphin [41]
4 years ago
12

Be sure to answer all parts.

Chemistry
1 answer:
Over [174]4 years ago
3 0

The dissociation constant is 2.44 mM.

<u>Explanation:</u>

Dissociation constant of any acid or any kind of solutions is the measure of amount dissolved in the solution or separated into different elements. So it is calculated as the ratio of product of concentration of dissociated elements to the concentration of the original compound.

Here the concentration of the acid [HA] = 0.035 M, the pH of the acid is given as 4.67.

pH=-log[H^{+}]

[H^{+}]=e^{-pH} = \frac{1}{e^{pH} } = \frac{1}{e^{4.67} } =\frac{1}{107}

[H^{+}]=9.35 \times 10^{-3}  M

Then, K_{a} =\frac{[H^{+}][A^{-}] }{[HA]} =\frac{(9.35 \times 10^{-3}) ^{2} }{0.035}\\ \\K_{a} = 2497.78 \times 10^{-6}

Thus, the dissociation constant is 2.44 mM.

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The complete question is:<em> An analytical chemist is titrating 182.2 mL of a 1.200 M solution of nitrous acid (HNO2) with a solution of 0.8400 M KOH. The pKa of nitrous acid is 3.35. Calculate the pH of the acid solution after the chemist has added 46.44 mL of the KOH solution to it.</em>

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The reaction of HNO₂ with KOH is:

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It is possible to find the pH of this buffer (<em>Mixture of a weak acid, HNO₂ with the conjugate base, NO₂⁻), </em>using H-H equation for this system:

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<h3>pH = 2.69</h3>
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