<h2>Hello!</h2>
The answer is:
The first measurement of volume is equal to 835.23 mL.
<h2>Why?</h2>
Boyle's Law equation can be used when the temperature is kept constant, and it establishes a relation between the pressure and volume, showing that when an ideal gas is kept constant, the pressure and volume are inversely proportional.
So, we Boyle's Law equation states that:
![P_{1}V_{1}=P_{2}V_{2}](https://tex.z-dn.net/?f=P_%7B1%7DV_%7B1%7D%3DP_%7B2%7DV_%7B2%7D)
Where,
![P_1=FirstPressure\\V_1=FirstVolume\\P_2=NewPressure\\V_2=NewVolume](https://tex.z-dn.net/?f=P_1%3DFirstPressure%5C%5CV_1%3DFirstVolume%5C%5CP_2%3DNewPressure%5C%5CV_2%3DNewVolume)
Now, if we are looking for the first volume measurement, we need to rewrite the equation as follow:
![P_{1}V_{1}=P_{2}V_{2}\\\\V_{1}=\frac{P_{2}V_{2}}{P_{1}}](https://tex.z-dn.net/?f=P_%7B1%7DV_%7B1%7D%3DP_%7B2%7DV_%7B2%7D%5C%5C%5C%5CV_%7B1%7D%3D%5Cfrac%7BP_%7B2%7DV_%7B2%7D%7D%7BP_%7B1%7D%7D)
So, substituting the given information and calculating, we have:
![V_{1}=\frac{8.59atm*527mL}{5.42atm}](https://tex.z-dn.net/?f=V_%7B1%7D%3D%5Cfrac%7B8.59atm%2A527mL%7D%7B5.42atm%7D)
![V_{1}=\frac{4526.93atm.mL}{5.42atm}=835.23mL](https://tex.z-dn.net/?f=V_%7B1%7D%3D%5Cfrac%7B4526.93atm.mL%7D%7B5.42atm%7D%3D835.23mL)
Hence, the first measurement of volume is equal 835.23 mL.
Have a nice day!