1) Chemical reaction
HCl + NaOH ---> NaCl + H2O
25.0 ml
0.150 M 0.250M
2) 50% completion => 0.025 l * 0.150 M * (1/2) = 0.001875 mol HCl consumed and 0.001875 mol HCl in solution
0.001875 mol HCl => 0.001875 mol H(+)
Volume = Volume of HCl solution + Volumen of NaOH solution added
Volume of HCl solution = 0.0250 l
Volume of NaOH = n / M = 0.001875 mol / 0.250M = 0.0075 l
Total volume = 0.0250 l + 0.0075 l = 0.0325 l
[H+] = 0.001875 mol / 0.0325 l = 0.05769 M
pH = - log [H+] = - log (0.05769) = 1.23
Answer: 1.23
3) Equivalence point
0.02500 l * 0.150 M = 0.250M * V
=> V = 0.02500 * 0.150 / 0.250 = 0.015 l
4) 1.00 ml NaOH added beyond the equivalence point
1.00 ml * 1 l / 1000 ml * 0.250 M = 0.00025 mol NaOH in excess
0.00025 mol NaOH = 0.00025 mol OH-
Volume of the solution = 0.02500 l + 0.015 l + 1.00/1000 l = 0.041 l
[OH-] = 0.00025 mol / 0.041 l = 0.00610 M
pOH = - log (0.00610) = 2.21
pH + pOH = 14 => pH = 14 - pOH = 14 - 2.21 = 11.76
Answer: 11.76
Answer:
Step 1 H2 + 2 NO → N2O + H2O (slow)
step 2 N2O + H2 → N2 + H2O (fast)
Explanation:
It is known that the slowest step in a reaction is the rate determining step in a sequence of reactions (reaction mechanism).
We have two important pieces of information in the question to guide our decision making process.
The overall reaction equation, and the rate expression. The two;
2 H2 + 2 NO → N2 + 2 H2O and rate = k[H2][NO]2 all support the answer given above.