Answer:
pKa of the histidine = 9.67
Explanation:
The relation between standard Gibbs energy and equilibrium constant is shown below as:
![\Delta{G^0} =-RT \ln \frac{[His]}{[His+]}](https://tex.z-dn.net/?f=%5CDelta%7BG%5E0%7D%20%3D-RT%20%5Cln%20%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
R is Gas constant having value = 0.008314 kJ / K mol
Given temperature, T = 293 K
Given, 
So, Applying in the equation as:-
![15\ kJ/mol=-0.008314\ kJ/Kmol\times 293\ K\times \ln \frac{[His]}{[His+]}](https://tex.z-dn.net/?f=15%5C%20kJ%2Fmol%3D-0.008314%5C%20kJ%2FKmol%5Ctimes%20293%5C%20K%5Ctimes%20%5Cln%20%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Thus,
![\frac{[His]}{[His+]}=e^{\frac{15}{-0.008314\times 293}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3De%5E%7B%5Cfrac%7B15%7D%7B-0.008314%5Ctimes%20293%7D)
![\frac{[His]}{[His+]}=0.00211](https://tex.z-dn.net/?f=%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D%3D0.00211)
Also, considering:-
![pH=pKa+log\frac{[His]}{[His+]}](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%5Cfrac%7B%5BHis%5D%7D%7B%5BHis%2B%5D%7D)
Given that:- pH = 7.0
So, 
<u>pKa of the histidine = 9.67</u>
Answer:
The correct answer is option c.
Explanation:
Formula used to determine an average atomic mass :
Mass of isotope Sb-121 = 120.904 amu
Fractional abundance of Sb-121 = 57.21% = 0.5721
Mass of isotope Sb-123 = 122.904 amu
Fractional abundance of Sb-123 = 42.79% = 0.4279
Average atomic mass of Sb:
O.N. of Na = +1
O.N. of O = -2
Let, O.N. of Tin = x
1*2 + x + -2*2 = 0
2+x-4 = 0
x-2 = 0
x = 2
SO OPTION C IS YOUR ANSWER......
