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sergey [27]
3 years ago
14

In a photoelectric effect experiment, electrons are ejected from a titanium surface (work function, 3 eV) following irradiation

with UV light. The energy of the incident UV light is 7.2 x 10-19 J.
(a) Calculate the wavelength of the ejected electrons.
(b) Calculate the wavelength of the incident UV light.
(c) would an iron surface (Ф-4.7 eV require a longer or shorter wavelength of light to eject electrons with the same wavelength calculated in part (a)? Briefly explain.
Chemistry
1 answer:
White raven [17]3 years ago
6 0

Explanation:

According to the Einstein law, it is known that

            h \times \nu = \phi + \frac{1}{2} mv^{2}

where,   h = energy of light

           \phi = work function

           m v^{2} = kinetic energy of electron

It is given that the value of h \nu is 7.2 \times 10^{-19} J. And,

               1 eV = 1.6 \times 10^{-19} J

Here,  \phi for titanium is 4.33 eV

          = (4.33 \times 1.6 \times 10^{-19}) J  

          = 6.928 \times 10^{-19} J

(a)   First of all, kinetic energy will be calculated as follows.

             \frac{1}{2}mv^{2} = h \nu - \phi

                         = (7.2 \times 10^{-19} - 6.92 \times 10^{-19}) J

                         = 0.272 \times 10^{-19} J

It is known that mass of electrons is equal to 9.109 \times 10^{-31} kg.

Therefore, mv^{2} = 0.544 \times 10^{-19} J

and,     (mv)^{2} = 9.109 \times 0.544 \times 10^{-19} \times 10^{-31}

                       = 4.955 \times 10^{-50}

                mv = 2.225 \times 10^{-25}

Now, the relation between wavelength and mv is as follows.

      \lambda = \frac{6.626 \times 10^{-34}}{2.225 \times 10^{-25}}

                   = 2.98 \times 10^{-9} m

Therefore, the wavelength of the ejected electrons is 2.98 \times 10^{-9} m.

(b)   It is known that relation between energy and wavelength is as follows.

               E = h \nu = \frac{hc}{\lambda}

                  \lambda = \frac{6.626 \times 10^{-34} \times 3 \times 10^{8}}{7.2 \times 10^{-19}}

                     = \frac{6.626 \times 3 \times 10^{-26}}{7.2 \times 10^{-19}}

                    = 2.76 \times 10^{-7} m

Hence, the wavelength of the ejected electrons is 2.76 \times 10^{-7} m.

(c)   For iron surface, \phi = 4.7 eV

                                       = (4.7 \times 1.6 \times 10^{-19}) J

                                       = 7.52 \times 10^{-19} J

Here, the value of \phi is more than the value of UV light source. Hence, we need a shorter wavelength light as we know that,

                  E \propto \frac{1}{\lambda}

Therefore, lesser will be the wavelength higher will be the energy.

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