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sergey [27]
3 years ago
14

In a photoelectric effect experiment, electrons are ejected from a titanium surface (work function, 3 eV) following irradiation

with UV light. The energy of the incident UV light is 7.2 x 10-19 J.
(a) Calculate the wavelength of the ejected electrons.
(b) Calculate the wavelength of the incident UV light.
(c) would an iron surface (Ф-4.7 eV require a longer or shorter wavelength of light to eject electrons with the same wavelength calculated in part (a)? Briefly explain.
Chemistry
1 answer:
White raven [17]3 years ago
6 0

Explanation:

According to the Einstein law, it is known that

            h \times \nu = \phi + \frac{1}{2} mv^{2}

where,   h = energy of light

           \phi = work function

           m v^{2} = kinetic energy of electron

It is given that the value of h \nu is 7.2 \times 10^{-19} J. And,

               1 eV = 1.6 \times 10^{-19} J

Here,  \phi for titanium is 4.33 eV

          = (4.33 \times 1.6 \times 10^{-19}) J  

          = 6.928 \times 10^{-19} J

(a)   First of all, kinetic energy will be calculated as follows.

             \frac{1}{2}mv^{2} = h \nu - \phi

                         = (7.2 \times 10^{-19} - 6.92 \times 10^{-19}) J

                         = 0.272 \times 10^{-19} J

It is known that mass of electrons is equal to 9.109 \times 10^{-31} kg.

Therefore, mv^{2} = 0.544 \times 10^{-19} J

and,     (mv)^{2} = 9.109 \times 0.544 \times 10^{-19} \times 10^{-31}

                       = 4.955 \times 10^{-50}

                mv = 2.225 \times 10^{-25}

Now, the relation between wavelength and mv is as follows.

      \lambda = \frac{6.626 \times 10^{-34}}{2.225 \times 10^{-25}}

                   = 2.98 \times 10^{-9} m

Therefore, the wavelength of the ejected electrons is 2.98 \times 10^{-9} m.

(b)   It is known that relation between energy and wavelength is as follows.

               E = h \nu = \frac{hc}{\lambda}

                  \lambda = \frac{6.626 \times 10^{-34} \times 3 \times 10^{8}}{7.2 \times 10^{-19}}

                     = \frac{6.626 \times 3 \times 10^{-26}}{7.2 \times 10^{-19}}

                    = 2.76 \times 10^{-7} m

Hence, the wavelength of the ejected electrons is 2.76 \times 10^{-7} m.

(c)   For iron surface, \phi = 4.7 eV

                                       = (4.7 \times 1.6 \times 10^{-19}) J

                                       = 7.52 \times 10^{-19} J

Here, the value of \phi is more than the value of UV light source. Hence, we need a shorter wavelength light as we know that,

                  E \propto \frac{1}{\lambda}

Therefore, lesser will be the wavelength higher will be the energy.

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2.19   :    2.19                                 2.19  : 6/4 × 2.19 = 3.285 mol

Now we will compare the moles of NO and H₂O with oxygen from balanced chemical equation:

O₂  :   NO                                               O₂ :   H₂O

5     :    4                                                  5     :    6

4.93   :   4/5×4.93 = 3.944 mol               4.93  : 6/5 × 4.93 = 5.916 mol

we can see that moles of water and nitrogen monoxide produced from the ammonia are less, so ammonia will be limiting reactant and will limit the product yield.

Mass of water = number of  moles × molar mass

Mass of water = 3.285 mol × 18 g/mol

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Mass of nitrogen monoxide  = number of  moles × molar mass

Mass of nitrogen monoxide = 2.19 mol × 30 g/mol

Mass of nitrogen monoxide = 65.7 g

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