Question

Pie times two is equivalent to two times pie

Answer 1

Of couse, YES. The multiplication operation admits the commutative property:

$\boxed{\pi*2=2*\pi}$

Answer 2

That's a true statement.  In fact, it doesn't even matter what the two numbers are.
'A' times 'B' is equal to 'B' times 'A', whatever they are.