Answer:
a. 113 min
Explanation:
Considering the equilibrium:-
2N₂O₅ ⇔ 4NO₂ + O₂
At t = 0 125 kPa
At t = teq 125 - 2x 4x x
Thus, total pressure = 125 - 2x + 4x + x = 125 - 3x
125 - 3x = 176 kPa
x = 17 kPa
Remaining pressure of N₂O₅ = 125 - 2*17 kPa = 91 kPa
Using integrated rate law for first order kinetics as:
![[A_t]=[A_0]e^{-kt}](https://tex.z-dn.net/?f=%5BA_t%5D%3D%5BA_0%5De%5E%7B-kt%7D)
Where,
![[A_t]](https://tex.z-dn.net/?f=%5BA_t%5D)
is the concentration at time t
![[A_0]](https://tex.z-dn.net/?f=%5BA_0%5D)
is the initial concentration
Given that:
The rate constant, k = 
min⁻¹
Initial concentration = 125 kPa
Final concentration = 91 kPa
Time = ?
Applying in the above equation, we get that:-
The question is incomplete, the complete question is
Which is NOT correct for when the silver and vanadium half-cells are connected via a salt bridge and a potentiometer? Ag^+ + 1 e^- rightarrow Ag Edegree = 0.7993 V V^2+ + 2e^- right arrow V E degree =-1.125 V Ag+ is reduced V is oxidized 1.924 V V2^+ is reduced Ag is oxidized I and II III, IV, and V I, II, and III III only IV and V
Answer:
only IV and V
Explanation:
If we look at the values of reduction potential for the two species, we will discover that vanadium has a negative reduction potential indicating its tendency towards oxidation.
On the other hand, solve has a positive reduction potential indicating a tendency towards reduction.
This implies that vanadium must be oxidized and silver reduced and not the not her way ground? Hence the answer above.
