the pressure of the gas increases
An orbital that penetrates into the region occupied by core electrons is less shielded from nuclear charge than an orbital that does not penetrate and therefore has a lower energy.
Explanation:
The only true statement from the given options is that "an orbital that penetrates into the region occupied by core electrons is less shielded from nuclear charge than an orbital that does not penetrate and therefore has a lower energy." Inner orbitals which are also known to contain core electrons feels the bulk of the nuclear pull on them compared to the outermost orbitals containing the valence electrons.
- The nuclear pull is the effect of the nucleus pulling and attracting the electrons in orbitals.
- This pull is stronger for inner orbitals and weak on the outer ones.
- The outer orbitals are said to be well shielded from the pull of the nuclear charge.
- Also, based on the quantum theory, electrons in the outer orbitals have higher energies because they occupy orbitals at having higher energy value.
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Alkenes on reacting with ozone results in the formation of ozonide which undergo reductive cleavage in presence of dimethyl sulfide to form carbonyl compounds (aldehyde or ketone). Whereas in presence of hydrogen peroxide it undergoes oxidative cleavage to form carboxylic acids or ketones.
Since, A alkene yields 4-heptanone only on treatment with ozone and DMS thus, it implies that both the chains on the side of the double-bond are similar the product is 4-heptanone that means the double bond is present between the chains at the 4th carbon. Therefore the structure of compound A is 4,5-dipropyloct-4-ene.
The reaction is as shown in the image.
The reaction of A with m-CPBA (meta-perchlorobenzoic acid) followed by aqueous acid 
is shown in the image.
m-CPBA (meta-perchlorobenzoic acid) is a peracid and forms epoxides on reacting with alkenes.
