Answer:To convert the model of one constitutional isomer to another constitutional isomer one needs to exchange 2 atoms/groups on different atoms.
To convert the model of one stereoisomer to another stereoisomer one needs to exchange 2 atoms/groups bonded to the same carbon.
To convert the model of one conformational isomer to another conformational isomer one only needs to rotate about single bond(s).
Explanation:
Constitutional isomers differ from each other in position of substituents. Hence if we interchange atoms or groups on two different atoms, we get constitutional isomers.
Stereo isomers posses different orientations in space. If two atoms or groups on the same carbon atoms interchange their spatial orientation, we have a different stereoisomer other than the original structure.
Conformers arise by free rotation across single bonds. Different conformers can be created by rotating single bonds.
Answer:
The concentration of COF₂ at equilibrium is 0.296 M.
Explanation:
To solve this equilibrium problem we use an ICE Table. In this table, we recognize 3 stages: Initial(I), Change(C) and Equilibrium(E). In each row we record the <em>concentrations</em> or <em>changes in concentration</em> in that stage. For this reaction:
2 COF₂(g) ⇌ CO₂(g) + CF₄(g)
I 2.00 0 0
C -2x +x +x
E 2.00 - 2x x x
Then, we replace these equilibrium concentrations in the Kc expression, and solve for "x".
![Kc=8.30=\frac{[CO_{2}] \times [CF_{4}] }{[COF_{2}]^{2} } =\frac{x^{2} }{(2.00-2x)^{2} } \\8.30=(\frac{x}{2.00-2x} )^{2} \\\sqrt{8.30} =\frac{x}{2.00-2x}\\5.76-5.76x=x\\x=0.852](https://tex.z-dn.net/?f=Kc%3D8.30%3D%5Cfrac%7B%5BCO_%7B2%7D%5D%20%5Ctimes%20%5BCF_%7B4%7D%5D%20%7D%7B%5BCOF_%7B2%7D%5D%5E%7B2%7D%20%7D%20%3D%5Cfrac%7Bx%5E%7B2%7D%20%7D%7B%282.00-2x%29%5E%7B2%7D%20%7D%20%5C%5C8.30%3D%28%5Cfrac%7Bx%7D%7B2.00-2x%7D%20%29%5E%7B2%7D%20%5C%5C%5Csqrt%7B8.30%7D%20%3D%5Cfrac%7Bx%7D%7B2.00-2x%7D%5C%5C5.76-5.76x%3Dx%5C%5Cx%3D0.852)
The concentration of COF₂ at equilibrium is 2.00 -2x = 2.00 - 2 × 0.852 = 0.296 M
Answer:
P₂ = 13.9 atm (3 sig. figs.)
Explanation:
The pressure (P), Volume (V) relationship with Temperature (T) & mass (n) held constant is an inverse proportionality. That is Boyles Law ...
P ∝ 1/V => P = k/V => k = P·V
For two pressure-volume conditions, the proportionality constant (k) remains constant where k₁ = k₂ and P₁·V₁ = P₂·V₂ => P₂ = P₁·V₁/V₂
Given:
P₁ = 1.31 atm.
V₁ = 5.51 L
P₂ = ?
V₂ = 0.520 L
V₂ = (1.31 atm)(5.51L)/(0.520L) = 13.88096154 atm (calc. ans.) = 13.9 atm (3 sig. figs.)
No more solute will dissolve at that temperature, the temperature would have to be increased in order for more solute to dissolve.
