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belka [17]
3 years ago
8

Given the Henry’s law constant for O2(4.34*109Pa) at 25° C, calculate the molar concentration of oxygen in air-saturated and O2s

aturated water. (4 points)
Chemistry
1 answer:
Flauer [41]3 years ago
8 0

This is an incomplete question, here is a complete question.

The Henry's law constant for oxygen dissolved in water is 4.34 × 10⁹ g/L.Pa at 25⁰C.If the partial pressure of oxygen in air is 0.2 atm, under atmospheric conditions, calculate the molar concentration of oxygen in air-saturated and oxygen saturated water.

Answer : The molar concentration of oxygen is, 2.67\times 10^2mol/L

Explanation :

As we know that,

C_{O_2}=k_H\times p_{O_2}

where,

C_{O_2} = molar solubility of O_2 = ?

p_{O_2} = partial pressure of O_2 = 0.2 atm  = 1.97×10⁻⁶ Pa

k_H = Henry's law constant  = 4.34 × 10⁹ g/L.Pa

Now put all the given values in the above formula, we get:

C_{O_2}=(4.34\times 10^9g/L.Pa)\times (1.97\times 10^{-6}Pa)

C_{O_2}=8.55\times 10^3g/L

Now we have to molar concentration of oxygen.

Molar concentration of oxygen = \frac{8.55\times 10^3g/L}{32g/mol}=2.67\times 10^2mol/L

Therefore, the molar concentration of oxygen is, 2.67\times 10^2mol/L

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puteri [66]

Answer:

Density, melting point. and magnetic properties  

Explanation:

I can think of three ways.

1. Density

The density of Cu₂S is 5.6 g/cm³; that of CuS is 4.76 g/cm³.

It should be possible to distinguish these even with high school equipment.

2. Melting point

Cu₂S melts at 1130 °C (yellowish-red); CuS decomposes at 500 °C (faint red).

A Bunsen burner can easily reach these temperatures.

3. Magnetic properties

You can use a Gouy balance to measure the magnetic susceptibilities.

In Cu₂S the Cu⁺ ion has a d¹⁰ electron configuration, so all the electrons are paired and the solid is diamagnetic.

In CuS the Cu²⁺ ion has a d⁹ electron configuration, so all there is an unpaired electron and the solid is paramagnetic.

A sample of Cu₂S will be repelled by the magnetic field and show a decrease in weight.

A sample of CuS will be attracted by the magnetic field and show an increase in weight.

In the picture below, you can see the sample partially suspended between the poles of an electromagnet.

 

6 0
3 years ago
Compute the number of grams(g) of lead in 22.5 moles of lead.
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Explanation:

hope this helps :).

7 0
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What would be the major product if 1,4-dibromo-4-methylpentane was allowed to react with:
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Answer : The correct answer for a) 4-bromo-2-iodo-4-methyl pentane and b)5-bromo-2-ethoxy-2-methyl pentane.

A) Reaction with NaI :

Reaction of alkyl halide with NaI is known as Finkelstein Reaction . The acetone is used as solvent . It involves bimolecular nucleophillic substitution rmechanism (SN²) . There is replecement of one halogen with other occurs .

The incoming Nucleophile(Nu⁻) (halide) attacks on carbon from back side , while the leaving group (halide) leaves the compound from front side , simultaneously. The product so formed have is inverted .(Image)

NaI releases I⁻ ion which act as nucelophile and attacks on C1 carbon and Br⁻ from C1 carbon is released . Out of two bromines at C1 and C4 carbons , C1 is primary carbon which is less sterically hindered while C-4 is tertiary carbon and sterically hindered . So it is easy for incoming Nu⁻ to attack on C1 carbon .So Br⁻ is repleaced by I⁻.

1,4-dibromo-4-methylpentane + NaI → 4-bromo-1-iodo-4-methylpentane

The product formed from reaction between 1,4-dibromo-4-methylpentane and NaI is 4-bromo-1-iodo-4-methylpentane . (Image)

B) Reaction with AgNO3 :

Reaction of alkyl halide with AgNO3 in ethanol takes place via SN¹ ( unimolecular nucleophilic substitution ) mechanism . In this leaving group(halide) leaves from alkyl halide forming an intermediate carbocation species . The incoming Nu⁻ attack on this carbocation.

AgNO3 reacts releases Ag⁺ion which abstract Br⁻ of C-4 carbon from 1,4-dibromo-4-methylpentane. THis forms tertiary carbocation which is more stable than carbocation formed by removal of Br from C-1 . The ethanol being more Nucleophilic than NO₃⁻ (from AgNO₃), attacks on this carbocation .(Image )

The product formed as a result is 5-bromo-2-ethoxy-2-methyl pentane.

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