The hydroxyl radical, a fragment of water vapor known as the "atmospheric cleanser", with a chemical formula of OH, has a global
ly averaged number density of ~1×10^6 molecules cm-3 that is fairly constant with altitude. Determine the OH mixing ratio (in ppt) at the surface, where total pressure P ~1 atm, temperature T ~282K, and also at 10 km altitude, where P ~0.260 atm,
1 answer:
Answer:
Check the explanation
Explanation:
The hydroxyl radical, •OH, is the hydroxide ion (OH−) when in neutral form of the Hydroxyl radicals they are extremely reactive (easily becoming hydroxy groups) and as a result are short-lived; however, they form a significant part of radical chemistry. The hydroxyl radical composition is also highly reactive towards oxidative reactions.
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Answer:
The appropriate answer is "9.225 g".
Explanation:
Given:
Required level,
= 63 ppm
Initial concentration,
= 22 ppm
Now,
The amount of free SO₂ will be:
=
=
=
The amount of free SO₂ to be added will be:
=
=
∵ 1000 mg = 1 g
So,
=
=
Thus,
"9.225 g" should be added.
Answer:
0.4 M
Explanation:
Equilibrium occurs when the velocity of the formation of the products is equal to the velocity of the formation of the reactants. It can be described by the equilibrium constant, which is the multiplication of the concentration of the products elevated by their coefficients divided by the multiplication of the concentration of the reactants elevated by their coefficients. So, let's do an equilibrium chart for the reaction.
Because there's no O₂ in the beginning, the NO will decompose:
N₂(g) + O₂(g) ⇄ 2NO(g)
0.30 0 0.70 Initial
+x +x -2x Reacts (the stoichiometry is 1:1:2)
0.30+x x 0.70-2x Equilibrium
The equilibrium concentrations are the number of moles divided by the volume (0.250 L):
[N₂] = (0.30 + x)/0.250
[O₂] = x/0.25
[NO] = (0.70 - 2x)/0.250
K = [NO]²/([N₂]*[O₂])
K =
7.70 = (0.70-2x)²/[(0.30+x)*x]
7.70 = (0.49 - 2.80x + 4x²)/(0.30x + x²)
4x² - 2.80x + 0.49 = 2.31x + 7.70x²
3.7x² + 5.11x - 0.49 = 0
Solving in a graphical calculator (or by Bhaskara's equation), x>0 and x<0.70
x = 0.09 mol
Thus,
[O₂] = 0.09/0.250 = 0.36 M ≅ 0.4 M