When solving these proportions we just remember when moving a number from one side to the other if it started in the numerator it ends up in the denominator and vice versa.
I'll do it in two steps here for teaching purposes; it's not too hard to go directly to the answer.
The empirical rule you're referring to is the 68-95-99.7 rule, which asserts that for a normal (bell-shaped) distribution, approximately 68% of the distribution lies within 1 standard deviation of the mean; 95% lies within 2 standard deviations of the mean; and 99.7% lies within 3 standard deviations of the mean.
Let be the random variable denoting vehicle speeds along this highway. We want to find . To use the rule, we need to rephrase this probability in terms of the mean and standard deviation.
Notice that , and . In other words, 61 and 79 both lie exactly 3 standard deviations away from the mean, so .