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tangare [24]
3 years ago
14

Consider the following reaction:

Chemistry
1 answer:
iren [92.7K]3 years ago
5 0

Answer:

A. ΔG° = 132.5 kJ

B. ΔG° = 13.69 kJ

C. ΔG° = -58.59 kJ

Explanation:

Let's consider the following reaction.

CaCO₃(s) → CaO(s) + CO₂(g)

We can calculate the standard enthalpy of the reaction (ΔH°) using the following expression.

ΔH° = ∑np . ΔH°f(p) - ∑nr . ΔH°f(r)

where,

n: moles

ΔH°f: standard enthalpy of formation

ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g)) - 1 mol × ΔH°f(CaCO₃(s))

ΔH° = 1 mol × (-635.1 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1206.9 kJ/mol)

ΔH° = 178.3 kJ

We can calculate the standard entropy of the reaction (ΔS°) using the following expression.

ΔS° = ∑np . S°p - ∑nr . S°r

where,

S: standard entropy

ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g)) - 1 mol × S°(CaCO₃(s))

ΔS° = 1 mol × (39.75 J/K.mol) + 1 mol × (213.74 J/K.mol) - 1 mol × (92.9 J/K.mol)

ΔS° = 160.6 J/K. = 0.1606 kJ/K.

We can calculate the standard Gibbs free energy of the reaction (ΔG°) using the following expression.

ΔG° = ΔH° - T.ΔS°

where,

T: absolute temperature

<h3>A. 285 K</h3>

ΔG° = ΔH° - T.ΔS°

ΔG° = 178.3 kJ - 285K × 0.1606 kJ/K = 132.5 kJ

<h3>B. 1025 K</h3>

ΔG° = ΔH° - T.ΔS°

ΔG° = 178.3 kJ - 1025K × 0.1606 kJ/K = 13.69 kJ

<h3>C. 1475 K</h3>

ΔG° = ΔH° - T.ΔS°

ΔG° = 178.3 kJ - 1475K × 0.1606 kJ/K = -58.59 kJ

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zvonat [6]

Answer:

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7 0
3 years ago
The combustion reaction of isopropyl alcohol is given below: C 3 H 7 O H ( l ) + 9 2 O 2 ( g ) → 3 C O 2 ( g ) + 4 H 2 O ( g ) T
jek_recluse [69]

Answer:

the heat of formation of isopropyl alcohol is -317.82 kJ/mol

Explanation:

The heat of combustion of isopropyl alcohol is given as follows;

C₃H₇OH (l) +(9/2)O₂ → 3CO₂(g) + 4H₂O (g)

The heat of combustion of CO₂ and H₂O are given as follows

C (s) + O₂ (g) → CO₂(g) = −393.50 kJ

H₂ (g) + 1/2·O₂(g)   →  H₂O (l) = −285.83 kJ

Therefore we have

3CO₂(g) + 4H₂O (g) → C₃H₇OH (l) +(9/2)O₂ which we can write as

3C (s) + 3O₂ (g) → 3CO₂(g) = −393.50 kJ × 3  =

4H₂ (g) + 2·O₂(g)   →  4H₂O (l) = −285.83 kJ × 4

3CO₂(g) + 4H₂O (g) → C₃H₇OH (l) +(9/2)O₂ = +2006 kJ/mol

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Therefore, the heat of formation of isopropyl alcohol = -317.82 kJ/mol.

3 0
3 years ago
A 0.2121g sample of an organic compound was burned in a stream of oxygen and the carbon dioxide produced was collected in a stre
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Answer:

The answer to your question is: 17.26% of carbon

Explanation:

Data

CxHy = 0.2121 g

BaCO₃ = 0.6006 g

Molecular mass BaCO₃ = 137 + 12 + 48 = 197 g

Reaction

                    CO₂  +  Ba(OH)₂  ⇒   BaCO₃  +  H₂O

Process

1.- Find the amount of carbon in BaCO₃

                              197 g of BaCO₃   ---------------  12 g of Carbon

                               0.6006 g           ----------------    x

                               x = (0.6006 x 12) / 197

                               x = 0.0366 g of carbon

2.- Calculate the percentage of carbon in the organic compound

           0.2121 g of organic compound  ---------------  100%

           0.0366g                                       --------------    x

                              x = (0.0366 x 100) / 0.2121

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nata0808 [166]

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If the Earth was formed 4,600 million years ago then the percentage of her age that the atmosphere has been in its composition is:

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