In a double helix DNA, adenine always pairs with thymine and cytosine pairs with guanine. Also, the two strands of a double helix DNA are antiparallel, that is, the 5' end of one strand lies opposite to the 3' end of another strand.
Therefore, a DNA strand with base sequence 5'-ATGC-3' would have a complementary strand 5'-GCAT-3'.