Answer:
[NO] = 1.72 x 10⁻³ M.
Explanation:
<em>2NO(g) ⇌ N₂(g)+O₂(g),</em>
Kc = [N₂][O₂] / [NO]².
- At initial time: [NO] = 0.171 M, [N₂] = [O₂] = 0.0 M.
- At equilibrium: [NO] = 0.171 M - 2x , [N₂] = [O₂] = x M.
∵ Kc = [N₂][O₂] / [NO]².
∴ 2400 = x² / (0.171 - 2x)² .
<u><em>Taking the aquare root for both sides:</em></u>
√(2400) = x / (0.171 - 2x)
48.99 = x / (0.171 - 2x)
48.99 (0.171 - 2x) = x
8.377 - 97.98 x = x
8.377 = 98.98 x.
∴ x = 8.464 x 10⁻².
<em>∴ [NO] = 0.171 - 2(8.464 x 10⁻²) = 1.72 x 10⁻³ M. </em>
<em>∴ [N₂] = [O₂] = x = 8.464 x 10⁻² M.</em>
Answer: The pH at equivalence point for the given solution is 5.59.
Explanation:
At the equivalence point,

So, first we will calculate the moles of
as follows.
= 0.0845 mol
Now, volume of
present will be calculated as follows.
Volume = 
= 
= 0.1891 L
Therefore, the total volume will be the sum of the given volumes as follows.
110 ml + 189.1 ml
= 299.13 ml
or, = 0.2991 L
Now, ![[CH_{3}NH_{3}^{+}] = \frac{0.0845 mol}{0.2991 L}](https://tex.z-dn.net/?f=%5BCH_%7B3%7DNH_%7B3%7D%5E%7B%2B%7D%5D%20%3D%20%5Cfrac%7B0.0845%20mol%7D%7B0.2991%20L%7D)
= 0.283 M
Chemical equation for this reaction is as follows.

As,
= 
= 
Now, ![[HNO_{3}] = \sqrt{k_{a}[CH_{3}NH_{3}^{+}]}](https://tex.z-dn.net/?f=%5BHNO_%7B3%7D%5D%20%3D%20%5Csqrt%7Bk_%7Ba%7D%5BCH_%7B3%7DNH_%7B3%7D%5E%7B%2B%7D%5D%7D)
= 
= 
Now, pH will be calculated as follows.
pH = ![-log [H_{3}O^{+}]](https://tex.z-dn.net/?f=-log%20%5BH_%7B3%7DO%5E%7B%2B%7D%5D)
= 
= 5.59
Thus, we can conclude that pH at equivalence point for the given solution is 5.59.
Answer:
23.8 torr
Explanation:
Vapor pressure of a liquid is simply the pressure of the vapor that arises when the liquid evaporates in a closed container above the liquid sample.
From the question given above, the vapor pressure is 23.8 torr at 25°C. Since the temperature is constant, the vapor will remain the same when equilibrium is reached in the new container as vapor pressure depends on the temperature of the liquid.