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a_sh-v [17]
3 years ago
10

The ΔG° of the hydrolysis reaction of ATP is –7.3 kcal/mole, but in a cell the actual ΔG is much more negative. What is the reas

on for the ΔG° and ΔG difference?
Chemistry
1 answer:
yanalaym [24]3 years ago
3 0

Answer:

ΔG° is for ideal (fixed) or standard conditions which cannot be found at the cellular level while ΔG is dependent on the quantities of reactants and products present at a specific time

Explanation:

ΔG° is fixed value for a given reaction that indicates the direction in which the reaction will proceed in a chemical equation under ideal conditions and because conditions within a cell varies and are unlike standard conditions, ΔG° cannot predict the direction of a cellular reaction at any given time. To predict the direction of progression of a reaction within the cell, ΔG is used, which depends on the amounts of the reactants and products present at a particular time

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Write a mechanism for the esterification of propanoic acid with 18O-labeled ethanol. Show clearly the fate of the 18O label. (b)
tatuchka [14]

Answer:

See explanation and images attached

Explanation:

a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.

b)  In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.

5 0
3 years ago
What is the molar mass of h2
alekssr [168]

Answer:

The answer is one

Explanation:

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3 0
3 years ago
How many amino acids can compose a protein molecule?
Vladimir79 [104]
The answer is A: Between 50 and 5,000 amino acids
3 0
2 years ago
Why does a cake rise when you bake it? ♡
VARVARA [1.3K]

The reaction of baking soda or baking powder with the liquid in the batter: These ingredients react together and cause air bubbles to form. ... Heat of the oven: The heat of the oven can cause baking powder to react further and cause more air bubbles, and the heat also sets the structure of the cake.

5 0
4 years ago
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The average bond energy (enthalpy) for a C=C double bond is 614 kJ/mol and that of a C−C single bond is 348 kJ/mol. Estimate the
AysviL [449]

Answer:

4.42x10⁻¹⁹ J/molecule

Explanation:

At a double bond, there's sigma and a pi bond, and at a single bond, there's only a sigma bond. Thus, if the energy to break both sigma and pi is 614 kJ/mol, and the energy to break only the sigma bond is 348 kJ/mol, the energy to break only the pi bond is:

E = 614 - 348 = 266 kJ/mol

Knowing that 1 kJ = 1000 J, E = 266,000 J/mol

By Avogadro's number, 1 mol = 6.02x10²³ molecules, thus:

E = 266,000 J/mol * 1mol/6.02x10²³ molecules

E = 4.42x10⁻¹⁹ J/molecule

7 0
3 years ago
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