pH of buffer can be calculated as:
pH=pKa+log[salt]/[Acid]
As ka = 4.58 x 10-4
Concentration of [Salt] that is NO2(-1)=0.380M
Concentration of [Acid] that is HNO2=0.500M
So, pH= -log(4.58*10^-4)+log((0.380)/0.500))
=3.21
So pH of solution will be 3.21
42cubic centimeter are in the block
volume is 48
One possible answer could be that a chemical reaction has occurred.
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Answer:
Qm = -55.8Kj/mole
Explanation:
NaOH(aq) + HNO₃(aq) => NaNO₃(aq) + H₂O(l)
Qm = (mc∆T)water /moles acid
Given => 100ml(0.300M) NaOH(aq) + 100ml(0.300M)HNO₃(aq)
=> 0.03mole NaOH(aq) + 0.03mole HNO₃(aq)
=> 0.03mole NaNO₃(aq) + 0.03mole H₂O(l)
ΔH⁰rxn = [(200ml)(1.00cal/g∙°C)(37 – 35)°C]water / 0.03mole HNO₃
= 13,333 cal/mole x 4.184J/cal = 55,787J/mol = 55.8Kj/mole (exothermic)*
Heat of reactions comes from formation of H-Oxy bonds on formation of water of reaction and heats the 200ml of solvent water from 35⁰C to 37⁰C.
