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andrey2020 [161]
3 years ago
13

The energy content of food is typically determined using a bomb calorimeter. Consider the combustion of a 0.22-g sample of butte

r in a bomb calorimeter having a heat capacity of 2.67 kJ/°C. If the temperature of the calorimeter increases from 23.5°C to 26.1°C, calculate the energy of combustion per gram of butter. Energy of combustion = kJ/g
Chemistry
1 answer:
iren2701 [21]3 years ago
8 0

Answer: The energy of combustion of butter is 31.5 kJ/g

Explanation:

The quantity of heat required to raise the temperature of a substance by one degree Celsius is called the specific heat capacity.

Q=C\times \Delta T

Q = Heat absorbed by calorimeter =?

C = heat capacity of calorimeter = 2.67kJ/^0C

Initial temperature of the calorimeter  = T_i = 23.5^0C

Final temperature of the calorimeter  = T_f  = 26.1^0C

Change in temperature ,\Delta T=T_f-T_i=(26.1-23.5)^0C=2.6^0C

Putting in the values, we get:

Q=2.67kJ/^0C\times 2.6^0C=6.94kJ

As heat absorbed by calorimeter is equal to heat released by combustion of butter

Q=q

Heat released by 0.22 g of butter = 6.94 kJ

Heat released by 1g of butter = \frac{6.94}{0.22}\times 1=31.5kJ

The energy of combustion of butter is 31.5 kJ/g

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Place the following solutions in order of increasing osmotic pressure. I. 0.15 M C2H6O2. II. 0.15 M MgCl2, III. 0.15 M NaCl, A.
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Answer:

D. I < III < II

Explanation:

  • The osmotic pressure (π) is given by the relation:

<em>π = iMRT.</em>

where, π is the osmotic pressure.

i is van 't Hoff factor.

M is the molarity of the solution.

R is the general gas constant.

T is the temperature.

<em>M, R and T are constant for all solutions.</em>

So, the osmotic pressure depends on the van 't Hoff factor.

  • The van 't Hoff factor is the ratio between the actual concentration of particles produced when the substance is dissolved and the concentration of a substance as calculated from its mass.
  • For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1.
  • For most ionic compounds dissolved in water, the van 't Hoff factor is equal to the number of discrete ions in a formula unit of the substance.

For C₂H₆O₂ (non-electrolyte solute): i = 1.

For MgCl₂: i = 3.

It dissociates to give (Mg²⁺ + 2Cl⁻).

For NaCl: i = 2.

It dissociates to give (Na⁺ + Cl⁻).

So, the solute that has the highest osmotic pressure is  II. 0.15 M MgCl₂, then III. 0.15 M NaCl, then I. 0.15 M C₂H₆O₂.

  • So, the answer is:

<em>D. I < III < II.</em>

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What is the volume of 45.0 grams of nitrogen monoxide , NO
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Answer:

V=37.05\ L

Explanation:

Given that:

Mass of NO, m = 45.0 g

Molar mass of NO, M = 30.01 g/mol

Temperature = 20.0 °C

The conversion of T( °C) to T(K) is shown below:

T(K) = T( °C) + 273.15  

So,  

T₁ = (20.0 + 273.15) K = 293.15 K

V = ?

Pressure = 740 mm Hg

Considering,  

n=\frac{m}{M}

Using ideal gas equation as:

PV=\frac{m}{M}RT

where,  

P is the pressure

V is the volume

m is the mass of the gas

M is the molar mass of the gas

T is the temperature  

R is Gas constant having value = 62.36367 L. mmHg/K. mol

Applying the values in the above equation as:-

740\times V=\frac{45.0}{30.01}\times 62.36367\times 293.15

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3 years ago
How many moles of copper are present in a sample of tennantite with a mass of 2290 grams?
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Answer:

               18.58 moles of Cu

Solution:

Data Given:

                  Chemical Formula of Tennantite  =  Cu₁₂As₄S₁₃

                  Mass of Cu₁₂As₄S₁₃  =  2290 g

                  M.Mass of Cu₁₂As₄S₁₃  =  1479.06 g.mol⁻¹

Step 1: Calculate Moles of Cu₁₂As₄S₁₃ as,

                               Moles  =  Mass ÷ M.Mass

Putting values,

                               Moles  =  2290 g ÷ 1479.06 g.mol⁻¹

                                Moles  =  1.548 mol

Step 2: Calculate Moles of Cu,

As,

                         1 mole of Cu₁₂As₄S₁₃ contains  =  12 moles of Cu

So,

               1.548 mol of Cu₁₂As₄S₁₃ will contain  =  X moles of Cu

Solving for X,

                     X  =  (1.548 mol × 12 mol) ÷ 1 mol

                     X  =  18.58 moles of Cu

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