1 and 2 are a metal - nonmetal pair - that kinda means ionic bond. Na and F are going to lose electrons.
3 [Nonmetals bond to each other covalently! <em>Ne</em> and <em>O </em>are nonmetals. <em>O </em>would need 2e to become stable. Either getting 2e (ionic bond) or sharing 2e (with <em>H</em>, for example). However, <em>Ne </em>is a noble gas, which means it is already doing fine with its 8e on its valence shell and isn't gonna share 2e of its electrons with <em>O</em>. So, despite the fact that they are both nonmetals, they won't form a covalent bond.
Sum up: they are 2 gases haha, and one of them is a noble one. They will never bond to each other covalently
4 - C and S - right answer
As they are both nonmetals (nonmetals bond to each other covalently, none of them is a noble gas, and so on)