The number of mole of HCl needed for the solution is 1.035×10¯³ mole
<h3>How to determine the pKa</h3>
We'll begin by calculating the pKa of the solution. This can be obtained as follow:
- Equilibrium constant (Ka) = 2.3×10¯⁵
- pKa =?
pKa = –Log Ka
pKa = –Log 2.3×10¯⁵
pKa = 4.64
<h3>How to determine the molarity of HCl </h3>
- pKa = 4.64
- pH = 6.5
- Molarity of salt [NaZ] = 0.5 M
- Molarity of HCl [HCl] =?
pH = pKa + Log[salt]/[acid]
6.5 = 4.64 + Log[0.5]/[HCl]
Collect like terms
6.5 – 4.64 = Log[0.5]/[HCl]
1.86 = Log[0.5]/[HCl]
Take the anti-log
0.5 / [HCl] = anti-log 1.86
0.5 / [HCl] = 72.44
Cross multiply
0.5 = [HCl] × 72.44
Divide both side by 72.44
[HCl] = 0.5 / 72.4
[HCl] = 0.0069 M
<h3>How to determine the mole of HCl </h3>
- Molarity of HCl = 0.0069 M
- Volume = 150 mL = 150 / 1000 = 0.15 L
Mole = Molarity x Volume
Mole of HCl = 0.0069 × 0.15
Mole of HCl = 1.035×10¯³ mole
<h3>Complete question</h3>
How many moles of HCl need to be added to 150.0 mL of 0.50 M NaZ to have a solution with a pH of 6.50? (Ka of HZ is 2.3 x 10 -5 .) Assume negligible volume of the HCl
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I think the correct answers are X2Y and X3Y, X2Y5 and X3Y5, and X4Y2 and X3Y,
for the following reason:
If you look at the combining masses of X and Y in
each of the two compounds,
The first compound contains 0.25g of X combined with
0.75g of Y
so the ratio (by mass) of X to Y = 1 : 3
The second compound contains 0.33 g of X combined with
0.67 g of Y
so the ratio (by mass) of X to Y = 1 : 2
Now, you suppose to prepare each of these two
compounds, starting with the same fixed mass of element Y ( I will choose 12g
of Y for an easy calculation!)
The first compound will then contain 4g of X and 12g
of Y
The second compound will then contain 6g of X and
12g of Y
<span>The ratio which combined
the masses of X and the fixed mass (12g) of Y
= 4 : 6
<span>or 2 : 3 </span>
So, the ratio of MOLES of X which combined with the
fixed amount of Y in the two compounds is also = 2 : 3 </span>
The two compounds given with the plausible formula must therefore contain
the same ratio.
Answer : This reaction is an exothermic reaction.
Explanation :
Endothermic reaction : It is defined as the chemical reaction in which the energy is absorbed from the surrounding.
In the endothermic reaction, the energy of reactant are less than the energy of product.
Exothermic reaction : It is defined as the chemical reaction in which the energy is released into the surrounding.
In the exothermic reaction, the energy of reactant are more than the energy of product.
Enthalpy of reaction : It is the difference between the energy of product and the reactant. It is represented as 
.
The balanced chemical reaction will be:
From the reaction we conclude that the heat energy is released during the reaction that means this reaction is an exothermic reaction.
Hence, the reaction is an exothermic reaction.
Bronsted - Lowry acid in the given reaction is NH₄, as it gives H⁺ ion.
<h3>What is Bronsted - Lowry acid?</h3>
According to the theory of Bronsted - Lowry, acids are those substances which gives H⁺ ion or proton in the aqueous medium.
Given chemical reaction is :
NH₄ + HPO₄²⁻ → NH₃ + H₂PO₄⁻
In the above reaction NH₄ is the Bronsted - Lowry acid as it gives H⁺ ion in the reaction and changes to NH₃ which is the conjugate base of NH₄. Whereas HPO₄²⁻ is the Bronsted - Lowry base as it accepts the H⁺ ion to form H₂PO₄⁻ which is the conjugate acid of it.
Hence, option (1) is correct, i.e. NH₄ is the Bronsted - Lowry acid.
To know more about Bronsted - Lowry acid, visit the below link:
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