Give the products of the reaction of butanal, with: (a) sodium borohydride, in methanol (b) hydrogen cyanide, with catalytic cya
nide (c) potassium dichromate in dilute sulfuric acid; (d) methanol, with a trace of acid catalyst; (e) ethylamine (CH3CH2NH2)
1 answer:
Answer:
Answers are given below
Explanation:
(a) Aldehyde groups are reduced by sodium borohydride in methanol to give alcohol.
So, butanal produces butanol on reaction with sodium borohydride in methanol.
(b) Aldehyde forms cyanohydrin when they are treated with HCN with catalytic cyanide.
(c) Aldehydes are oxidized by potassium dichromate in dil. sulphuric acid to produce carboxylic acid.
(d) Aldehyde produces acetal with methanol and a trace amount of acid catalyst.
(e) Aldehyde gives condensation reaction with to produce imine.
Structures of products for the given reaction has been shown below.
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Answer:
11552.45 years
Explanation:
Given that:
Half life = 5730 years
Where, k is rate constant
So,
The rate constant, k = 0.00012 years⁻¹
Using integrated rate law for first order kinetics as:
Where,
is the concentration at time t
is the initial concentration
Given that:
The rate constant, k = 0.00012 years⁻¹
Initial concentration = 160.0 counts/min
Final concentration = 40.0 counts/min
Time = ?
Applying in the above equation, we get that:-