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Alchen [17]
3 years ago
14

Wenzhou prepares 200 mL of a solution of SnCl4in which the concentration ofchloride ions is 0.240M.a) What is the molarity of th

e SnCl4solution (i.e. what should the bottle be labeled)?b) What mass of SnCl4did Wenzhou use?
Chemistry
2 answers:
nalin [4]3 years ago
7 0

Answer:  a) 0.06 M

b) 3.13 grams.

Explanation:

Molarity of a solution is defined as the number of moles of solute dissolved per Liter of the solution.

Molarity=\frac{moles}{\text {Volume in L}}

Moles of  Cl^-=Molarity\times {\text {Volume in L}}=0.240\times 0.2L=0.048moles

The balanced reaction for dissociation will be:

SnCl_4\rightarrow Sn^{4+}+4Cl^{-}

Thus for 4 moles of Cl^-, there is 1 mole of SnCl_4

Thus moles of SnCl_4=\frac{1}{4}\times 0.048=0.012

Molarity of SnCl_4=\frac{moles}{\text {Volume in L}}=\frac{0.012}{0.2L}=0.06M

Thus the molarity of the  SnCl_4 solution = 0.06 M

b) Mass of SnCl_4= moles\times {\text {Molar mass}}=0.012mol\times 260.522g/mol=3.13g

Thus mass of  SnCl_4 Wenzhou use is 3.13 grams.

Nataliya [291]3 years ago
4 0

Answer:

a) M_{SnCl_4}=0.06M

b) m_{SnCl_4}=3.126gSnCl_4

Explanation:

Hello,

a) In this case, as ideally we have 0.240 moles of chloride ions per liter of solution, one computes the actual molarity of SnCl₄ as shown below via dimensional analysis:

M_{SnCl_4}=0.240\frac{molCl^-}{1Lsln} *\frac{1molSnCl_4}{4molCl^-}=0.06\frac{molSnCl_4}{L} =0.06M

b) Now, since Wenzhou prepared 200 mL, the used mass is computed as follows, in which the molar mass of SnCl₄ is considered:

m_{SnCl_4}=0.06\frac{molSnCl_4}{Lsln}*0.200Lsln*\frac{260.5gSnCl_4}{1molSnCl_4} \\m_{SnCl_4}=3.126gSnCl_4

Best regards.

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pickupchik [31]

Answer: There are 1.469 \times 10^{23} molecules present in 7.62 L of CH_4 at 87.5^{o}C and 722 torr.

Explanation:

Given : Volume = 7.62 L

Temperature = 87.5^{o}C = (87.5 + 273) K = 360.5 K

Pressure = 722 torr

1 torr = 0.00131579

Converting torr into atm as follows.

722 torr = 722 torr \times \frac{0.00131579 atm}{1 torr}\\= 0.95 atm

Therefore, using the ideal gas equation the number of moles are calculated as follows.

PV = nRT

where,

P = pressure

V = volume

n = number of moles

R = gas constant = 0.0821 L atm/mol K

T = temperature

Substitute the values into above formula as follows.

PV = nRT\\0.95 atm \times 7.62 L = n \times 0.0821 L atm/mol K \times 360.5 K\\n = \frac{0.95 atm \times 7.62 L}{0.0821 L atm/mol K \times 360.5 K}\\= \frac{7.239}{29.59705}\\= 0.244 mol

According to the mole concept, 1 mole of every substance contains 6.022 \times 10^{23} atoms. Hence, number of atoms or molecules present in 0.244 mol are calculated as follows.

0.244 mol \times 6.022 \times 10^{23}\\= 1.469 \times 10^{23}

Thus, we can conclude that there are 1.469 \times 10^{23} molecules present in 7.62 L of CH_4 at 87.5^{o}C and 722 torr.

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As the temperature drops or decreases, the water molecules gradually slow down. Eventually they stop moving and simply vibrate back and forth. At this point ice is formed, the solid phase of water. If the temperature is allowed to increase, the molecules will once again begin to vibrate faster and faster.

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A mixture of CO2 and Kr weighs 35.0 g and exerts a pressure of 0.708 atm in its container. Since Kr is expensive, you wish to re
ollegr [7]

Explanation:

Since, it is given that carbon dioxide is completely removed by absorption with NaOH. And, pressure inside the container is 0.250 atm.

For Kr = 0.250 atm and pressure CO_{2} will be calculated as follows.

           CO_{2} = (0.708 - 0.250) atm

                       = 0.458 atm

Now, we will calculate the mole fraction as follows.

            CO_{2} = \frac{0.458}{0.708}

                       = 0.646

               Kr = \frac{0.250}{0.708}

                    = 0.353

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              CO_{2} = 0.646 \times 44

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                        = 29.57

Therefore, total mass is calculated as follows.

           Total mass = (28.424 + 29.57)

                              = 57.994

Hence, the percentage of CO_{2} and Kr are calculated as follows.

          CO_{2} = \frac{28.424}{57.99} \times 100

                     = 49%

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                    = 51%

Hence, amount of CO_{2} and Kr present i mixture is as follows.  

         CO_{2} in mixture = 35 \times 0.49

                             = 17.15 g

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                       = 17.85 g

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Explanation:

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<em>ΔTf = Kf.m,</em>

ΔTf is the depression in the freezing point of tert-Butyl alcohol (ΔTf = freezing point of pure solvent - freezing point in presence of unknown liquid = 25.5°C - 15.3°C = 10.2°C).

Kf is the molal freezing point constant of tert-Butyl alcohol (Kf = 9.1 °C/m).

m is the molality of unknown liquid.

∵ ΔTf = Kf.m

<em>∴ m = ΔTf/Kf </em>= (10.2°C)/(9.1 °C/m) = <em>1.121 m.</em>

  • We need to calculate the molar mass of the unknown liquid:

Molality (m) is the no. of moles of solute in 1.0 kg of solvent.

∴ m = (mass/molar mass) of unknown liquid/(mass of tert-Butyl alcohol (kg))

m = 1.121 m, mass of unknown liquid = 0.807 g, mass of tert-Butyl alcohol = 11.6 g = 0.0116 kg.

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<em></em>

  • So, the unknown liquid is:

<em>ethylene glycol (molar mass = 62.07 g/mol).</em>

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