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Fittoniya [83]
3 years ago
6

A gaseous mixture at 265K and 1.0 atm contains 25 O2 60 N2 and 15 CO2 mole basis The velocities of the components are 0.084 cm s

O2 0.120 cm s N2 and 0.052 cm s CO2 Find the N2 diffusion velocity relative to the mole average velocity and the molar diffusional flux of N2
Chemistry
1 answer:
Free_Kalibri [48]3 years ago
8 0

Answer:

The molar average velocity is 0.0588 cm/s

The N₂ diffusion velocity relative to the mole average velocity is -0.1428 cm/s

The molar diffusional flux of N₂ is -3.9x10⁻³

Explanation:

Given data:

T = temperature = 265 K

O₂ = 25%

N₂ = 60%

CO₂ = 15%

vO₂ = -0.084 cm/s

vN₂ = 0.12 cm/s

vCO₂ = 0.052 cm/s

The molar average velocity is equal:

v_{av} =(0.25*(-0.084))+(0.6*0.12)+(0.15*0.052)=0.0588cm/s

The N₂ diffusion velocity relative to the molar average velocity is:

v_{i} -v_{av} =-0.084-0.0588=-0.1428cm/s

The molar diffusional flux of N₂ is:

N_{N_{2} } =\frac{P}{RT} y_{A} (v_{i} -v_{av} )=-3.9x10^{-3}

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Carbon tetrachloride can be produced by the following reaction: Suppose 1.20 mol of and 3.60 mol of were placed in a 1.00-L flas
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The given question is incomplete. The complete question is :

Carbon tetrachloride can be produced by the following reaction:

CS_2(g)+3Cl_2(g)\rightleftharpoons S_2Cl_2(g)+CCl_4(g)

Suppose 1.20 mol CS_2(g) of and 3.60 mol of Cl_2(g)  were placed in a 1.00-L flask at an unknown temperature. After equilibrium has been achieved, the mixture contains 0.72 mol  of CCl_4. Calculate equilibrium constant at the unknown temperature.

Answer: The equilibrium constant at unknown temperature is 0.36

Explanation:

Moles of  CS_2 = 1.20 mole

Moles of  Cl_2 = 3.60 mole

Volume of solution = 1.00  L

Initial concentration of CS_2 = \frac{moles}{volume}=\frac{1.20mol}{1L}=1.20M

Initial concentration of Cl_2 = \frac{moles}{volume}=\frac{3.60mol}{1L}=3.60M

The given balanced equilibrium reaction is,

                 CS_2(g)+3Cl_2(g)\rightleftharpoons S_2Cl_2(g)+CCl_4(g)

Initial conc.         1.20 M        3.60 M                  0                  0

At eqm. conc.     (1.20-x) M   (3.60-3x) M   (x) M        (x) M

The expression for equilibrium constant for this reaction will be,

K_c=\frac{[S_2Cl_2]\times [CCl_4]}{[Cl_2]^3[CS_2]}

Now put all the given values in this expression, we get :

K_c=\frac{(x)\times (x)}{(3.60-3x)^3\times (1.20-x)}

Given :Equilibrium concentration of CCl_4 , x = \frac{moles}{volume}=\frac{0.72mol}{1L}=0.72M

K_c=\frac{(0.72)\times (0.72)}{(3.60-3\times 0.72)^3\times (1.20-0.72)}

K_c=0.36

Thus equilibrium constant at unknown temperature is 0.36

4 0
2 years ago
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