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nevsk [136]
3 years ago
10

HBr can be added to alkenes in either the absence or presence of peroxides (producing either the Markovnikov or the anti-Markovn

ikov addition product). What intermediates leading to the formation of the major product are observed when 1-butene is treated with 1) HBr or 2) HBr/peroxides?

Chemistry
1 answer:
Dmitrij [34]3 years ago
3 0

Answer:

1) 2-bromobutane

2) 1-bromobutane

Explanation:

In the HBr reaction, we will have a <u>markovniknov reaction</u> due to the <u>carbocation formation</u>. The Br- then would be added in the <u>most substituted</u> carbon of the double bond.

In the HBr/peroxide reaction we have the opposite case: an <u>anti-markovnikov reaction</u>. Therefore the Br- would be added in the <u>least substitued</u> carbon of the double bond.

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