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inn [45]
4 years ago
15

A 4.05 sample of an unknown gas at 35 C and 1.00 atm is stored in a 2.85 L flask.

Chemistry
2 answers:
lara31 [8.8K]4 years ago
7 0

Answer:

1.35 g/L

Explanation:

1) Use PV = nRT to determine moles of gas present in gas:

(1.10 atm) (2.55 L) = (n) (0.08206) (328 K)

n = 0.104 mol

2) Get molar mass of gas using calculated moles:

0.104 mol x M g/mol = 3.45g

M = 3.45 g / 0.104 mol = 33.17 g/mol

Density = Molar Mass x P / RT

= 33.17 g/mol x 1.10 atm / 0.0821 L mol / atm .K x 328 K

= 1.35 g /L

Dennis_Churaev [7]4 years ago
6 0

<u>Answer:</u>

The density of the gas is 1.42g/L and the molar mass is 32.92 g/mol

<u>Explanation:</u>

Mass of the unknown gas=m= 4.05g

Temperature=T= 35C

Pressure exerted upon the unknown gas= P= 1 atm

Volume of the flask=V= 2.85 L

Density=    ?  

Density= \frac{mass of the unknown gas}{ volume of the container containing the gas}

= \frac{m}{V}

=\frac{4.05}{2.85}

=1.421= 1.42g/L

Molar mass of the gas=M=?

Now,

As the formula is defined  

\frac{n}{V}=\frac{P}{RT}

n=\frac{VP}{RT}

(R= 0.082 L atm /K mol)

Since Temperature= 35C= (35+273) K

=308 K

n=\frac{2.85\times 1}{0.082\times 308}

n=\frac{2.85}{25.26}

n=0.1129 moles

Molar mass= M=\frac{m}{n}

=\frac{4.05}{0.123}

=32.92 g/mol

Hence the density of the gas is 1.42 g/L and the molar mass is 32.92 g/mol

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ddd [48]

Answer :

The enthalpy of reaction is, -187.6 kJ/mol

The total heat will be, -2251 kJ

Explanation :

According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.

According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.

(a) The formation of CH_4 will be,

2C(coal)+2H_2O(g)\rightarrow CH_4(g)+CO_2(g)    \Delta H_{rxn}=?

The intermediate balanced chemical reaction will be,

(1) C(coal)+H_2O(g)\rightarrow CO(g)+H_2(g)     \Delta H_1=29.7kJ

(2) CO(g)+H_2O(g)\rightarrow CO_2(g)+H_2(g)    \Delta H_2=-41kJ

(3) CO(g)+3H_2(g)\rightarrow CH_4(g)+H_2O(g)    \Delta H_3=-206kJ

We are multiplying equation 1 by 2 and then adding all the equations, we get :

(b) The expression for enthalpy of reaction will be,

\Delta H_{rxn}=2\times \Delta H_1+\Delta H_2+\Delta H_3

\Delta H_{rxn}=(2\times 29.7)+(-41)+(-206)

\Delta H_{rxn}=-187.6kJ/mol

Therefore, the enthalpy of reaction is, -187.6 kJ/mol

(c) Now we have to calculate the total heat.

\Delta H=\frac{q}{n}

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q=\Delta H\times n

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\Delta H = enthalpy change = -187.6 kJ/mol

q = heat = ?

n = number of moles of coal = \frac{1.00\times 1000g}{12.00g/mol}=83.33mol

Now put all the given values in the above formula, we get:

q=(-187.6kJ/mol)\times (83.33mol)=-2.251kJ

Thus, the total heat will be, -2251 kJ

4 0
4 years ago
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