Explain why the benzene molecule usually reacts with electrophiles
2 answers:
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Answer:
C) In[reactant] vs. time
Explanation:
For a first order reaction the integrated rate law equation is:
where A(0) = initial concentration of the reactant
A = concentration after time 't'
k = rate constant
Taking ln on both sides gives:
Therefore a plot of ln[A] vs t should give a straight line with a slope = -k
Hence, ln[reactant] vs time should be plotted for a first order reaction.
Rate law for the given 2nd order reaction is:
Rate = k[a]2
Given data:
rate constant k = 0.150 m-1s-1
initial concentration, [a] = 0.250 M
reaction time, t = 5.00 min = 5.00 min * 60 s/s = 300 s
To determine:
Concentration at time t = 300 s i.e.
Calculations:
The second order rate equation is:
substituting for k,t and [a] we get:
1/[a]t = 0.150 M-1s-1 * 300 s + 1/[0.250]M
1/[a]t = 49 M-1
[a]t = 1/49 M-1 = 0.0204 M
Hence the concentration of 'a' after t = 5min is 0.020 M