Answer:
Molar absorptivity or molar extinction co-effecient = 2120.14 cm⁻¹M⁻¹
Explanation:
First convert Concentration from ppm inM or mol/l
⇒ Molar mass of KMnO₄ = 158.03 g
⇒ 4.48 ppm = 4.48 mg/l = 4.48 x 10⁻³ g/l
⇒ Molarity = 
= 2.83 x 10⁻⁵ molar
Absorbance (A) = - log(T) ( T = % transmittance)
= - log(0.859)
= 0.06
According to Lambert Beer's law
ε = 
or, ε = 
or, ε = 2120.14 cm⁻¹M⁻¹
Where
ε = Molar absorptivity
A = absorbance
C = Molar concentration of KMnO₄ solution
l = length
This question includes four answer choices:
A. definite volume, highest molecular motion, highest kinetic energy
B. indefinite volume, least molecular motion, highest kinetic energy
C. definite volume, least molecular motion, lowest kinetic energy
D. definite volume, no molecular motion, lowest kinetic energy
Solids do not have the highest molecular motion (on the contrary they have the least molecular motion), so you can discard option A. Solids have a definite volume and the highest kinetic energy (given that they have the least molecular motion), so you discard option C. Molecules always have a vibrational motion, so you discard option D. Option C, have only characteristics that correctly describes a solid: definite volume, least molecular motion, lowest kinetic energy. Therefore, the answer is the option C.
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To determine the time it takes to completely vaporize the given amount of water, we first determine the total heat that is being absorbed from the process. To do this, we need information on the latent heat of vaporization of water. This heat is being absorbed by the process of phase change without any change in the temperature of the system. For water, it is equal to 40.8 kJ / mol.
Total heat = 40.8 kJ / mol ( 1.50 mol ) = 61.2 kJ of heat is to be absorbed
Given the constant rate of 19.0 J/s supply of energy to the system, we determine the time as follows:
Time = 61.2 kJ ( 1000 J / 1 kJ ) / 19.0 J/s = 3221.05 s
Answer:
5.6 seconds
Explanation:
The reaction follows a zero-order in dinitrogen monoxide
Rate = k[N20]^0 = change in concentration/time
[N20]^0 = 1
Time = change in concentration of N2O/k
Initial number of moles of N2O = 300 mmol = 300/1000 = 0.3 mol
Initial concentration = moles/volume = 0.3/4 = 0.075
Number of moles after t seconds = 150 mmol = 150/1000 = 0.15 mol
Concentration after t seconds = 0.15/4 = 0.0375 M
Change in concentration of N2O = 0.075 - 0.0375 = 0.0375 M
k = 0.0067 M/s
Time = 0.0375/0.0067 = 5.6 s
2K + Br2 ===> 2KBr
It's very ionic. The transfer of 2 electrons from K to Br2 is nearly as complete as it can be.
