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Otrada [13]
3 years ago
7

Calcular la m y M de una concentración Porcentual 45% m/m, la cual tiene una D solución 1.25 g/ml y una masa de sto de 125g.HN03

Chemistry
1 answer:
ioda3 years ago
8 0

Explanation:

Calculate the "m" and "M" of a percentage concentration of 45% m / m, which has a solution D 1.25 g / ml and a mass of 125g.

Given data is:

The mass % of the solution is 45%.

The density of the solution is 1.25 g/mL.

The mass of the solution is 125 g.

Molarity of solution is:

M=\frac{number of moles of solute}{volume of solution}

The volume of the solution is:

Volume=\frac{mass}{density} \\=125 g / 1.25 g/ml\\=100 mL

From mass% of the solution, the mass of solute HNO_3 can be calculated.

mass percent=\frac{mass of solute}{ mass of solution} \\45=(mass of HNO_3/125 g)x100\\\\mass of solute = 56.25g

The number of moles of HNO3 is :

n_H_N_O__3=\frac{m_H_N_O__3}{M_H_N_O__3}

=56.25 g/63.00g/mol\\\\=0.893mol

The molarity is:

M=n/V\\M=0.893 mol/0.1L\\M=8.93 M

The molality is:

m=n/mass of solvent in kg\\   =0.893 mol /(0.125-0.05625)kg\\  = 12.9 m

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Answer:

V=0.0310L=3.10mL

Explanation:

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In this case, since the acid is monoprotic and the KOH has one hydroxyl ion only, we can see that at the equivalence point the moles of both of them are the same:

n_{acid}=n_{KOH}

Thus, since we are given 1.70 g of the acid, we compute the moles of acid that were titrated:

n_{acid}=1.70g*\frac{1mol}{84.48g}=0.0201mol

Which equal the moles of KOH. In such a way, since the molarity is defined as moles over liters (M=n/V), the liters are moles over molarity (V=n/M), thus, the resulting volume is:

V=\frac{0.0201mol}{0.650mol/L}\\\\V=0.0310L=3.10mL

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1.15 g of a metallic element needs 300 cm3 of oxygen for complete reaction, at 298 K and 1 atm
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1) Calculate the number of moles of O2 (g) in 300 cm^3 of gas at 298 k and 1 atm


Ideal gas equation: pV = nRT => n = pV / RT


R = 0.0821 atm*liter/K*mol

V = 300 cm^3 = 0.300 liter

T = 298 K

p = 1 atm


=> n = 1 atm * 0.300 liter / [ (0.0821 atm*liter /K*mol) * 298K] = 0.01226 mol


2) The reaction of a metal with O2(g) to form an ionic compound (with O2- ions) is of the type


X (+) + O2 (g) ---> X2O          or   


2 X(2+) + O2(g) ----> X2O2 = 2XO     or


4X(3+) + 3O2(g) ---> 2X2O3


 
In the first case, 1 mol of metal react with 1 mol of O2(g); in the second case, 2 moles of metal react with 1 mol of O2(g); in the third, 4 moles of X react with 3 moles of O2(g)



So, lets probe those 3 cases.


3) Case 1: 1 mol of metal X / 1 mol O2(g) = x moles / 0.01226 mol

=> x = 0.01226 moles of metal X


Now you can calculate the atomic mass of the hypotethical metal:

1.15 grams / 0.01226 mol = 93.8 g / mol


That does not correspond to any of the metal with valence 1+


So, now probe the case 2.



4) Case 2:


2moles X metal / 1 mol O2(g) = x / 0.01226 mol


=> x = 2 * 0.01226 = 0.02452 mol


And the atomic mass of the metal is: 1.15 g / 0.02452 mol = 46.9 g/mol


That is similar to the atomic mass of titanium which is 47.9 g / mol and whose valece is 2+.


4) Case 3


4 mol meta X / 3 mol O2 = x / 0.01226 => x = 0.01226 * 4 / 3 = 0.01635 


atomic mass = 1.15 g / 0.01635 mol = 70.33 g/mol


That does not correspond to any metal.


Conclusion: the identity of the metallic element could be titanium.
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