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lozanna [386]
3 years ago
6

The standard molar enthalpy of formation of NH3(g) is -45.9 kJ/mol. What is the enthalpy change if 9.51 g N2(g) and 1.96 g H2(g)

react to produce NH3(g)
Chemistry
1 answer:
Vladimir [108]3 years ago
3 0

Answer:

\Delta H=-29.7kJ

Explanation:

Hello!

In this case, since the undergoing chemical reaction is:

N_2+3H_2\rightarrow 2NH_3

We first need to identify the limiting reactant given the masses of nitrogen and hydrogen:

n_{NH_3}^{by\ H_2}=1.96gH_2*\frac{1molH_2}{2.02gH_2}*\frac{2molNH_3}{3molH_2}=0.647molNH_3\\\\  n_{NH_3}^{by\ N_2}=9.51gN_2*\frac{1molN_2}{28.02gN_2}*\frac{2molNH_3}{1molN_2}=0.679molNH_3

It means that only 0.647 moles of ammonia are yielded, so the resulting enthalpy change is:

\Delta H=0.647molNH_3*\frac{-45.9kJ}{1molNH_3}\\\\ \Delta H=-29.7kJ

Best regards!

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Acid &amp; Base Calculations Calculate the hydronium ion concentration for each. Tell whether it is an acid or a base. 1. pH = 5
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<u>Explanation:</u>

pH is the negative logarithm of hydronium ion concentration present in a solution.

  • If the solution has high hydrogen ion concentration, then the pH will be low and the solution will be acidic. The pH range of acidic solution is 0 to 6.9
  • If the solution has low hydrogen ion concentration, then the pH will be high and the solution will be basic. The pH range of basic solution is 7.1 to 14
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To calculate the pH of the solution, we use equation:

pH=-\log[H_3O^+]     ......(1)

To calculate the pOH of the solution, we use the equation:

pH + pOH = 14                ........(2)

  • <u>For 1:</u>

We are given:

pH = 5.54

Putting values in equation 1, we get:

5.54=-\log[H_3O^+]

[H_3O^+]=2.88\times 10^{-6}M

Now, putting values in equation 2, we get:

14 = 5.54 + pOH

pOH = 8.46

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We are given:

pOH = 9.7

Putting values in equation 2, we get:

14 = 9.7 + pH

pH = 4.3

Now, putting values in equation 1, we get:

4.3=-\log[H_3O^+]

[H_3O^+]=5.012\times 10^{-5}M

The solution is acidic in nature.

  • <u>For 3:</u>

We are given:

pH = 7.0

Putting values in equation 1, we get:

7.0=-\log[H_3O^+]

[H_3O^+]=1.00\times 10^{-7}M

Now, putting values in equation 2, we get:

14 = 7.0 + pOH

pOH = 7.0

The solution is neither acidic nor basic in nature.

  • <u>For 4:</u>

We are given:

pH = 12.9

Putting values in equation 1, we get:

12.9=-\log[H_3O^+]

[H_3O^+]=1.26\times 10^{-13}M

Now, putting values in equation 2, we get:

14 = 12.9 + pOH

pOH = 1.1

The solution is basic in nature.

  • <u>For 5:</u>

We are given:

pOH = 1.2

Putting values in equation 2, we get:

14 = 1.2 + pH

pH = 12.8

Now, putting values in equation 1, we get:

12.8=-\log[H_3O^+]

[H_3O^+]=1.58\times 10^{-13}M

The solution is basic in nature.

  • <u>For 6:</u>

We are given:

[H_3O^+]=1\times 10^{-5}M

Putting values in equation 1, we get:

pH=-\log(1\times 10^{-5})

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Now, putting values in equation 2, we get:

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pOH = 9

The solution is acidic in nature.

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The quantity of heat given off, ΔH°rxn = 64.8KJ/mol = 64800J/mol

Number of moles of CaO = mass/molar mass, where molar mass of Ca0 = 56g/mol, mass of CaO = 10.1g

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Quantity of heat given off by 0.179 moles = 64800 *0.179 = 11599.2J/mol

Using the formula, <em>Quantity of heat, q = mass * specific heat capacity * temperature rise.</em>

mass of mixture = (10.1 + 157)g = 167.1g, Initial temperature = 18.0°C

Final temperature(T₂) - Initial temperature(T₁) = Temperature rise

11599.2J/mol = 167.1g * 4.18J/g·°C * ( T₂ - 18.0°C)

11599.2 = 698.478T₂ - 12572.604

11599.2 + 12572.604 = 698.478T₂

698.478T₂ = 24171.804

T₂ = 34.6°C

Therefore, final temperature attained by water = 34.6°C

6 0
3 years ago
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