<u>Ans: Acetic acid = 90.3 mM and Sodium acetate = 160 mM</u>
Given:
Acetic Acid/Sodium Acetate buffer of pH = 5.0
Let HA = acetic acid
A- = sodium acetate
Total concentration [HA] + [A-] = 250 mM ------(1)
pKa(acetic acid) = 4.75
Based on Henderson-Hasselbalch equation
pH = pKa + log[A-]/[HA]
[A-]/[HA] = 10^(pH-pKa) = 10^(5-4.75) = 10^0.25 = 1.77
[A-] = 1.77[HA] -----(2)
From (1) and (2)
[HA] + 1.77[HA] = 250 mM
[HA] = 250/2.77 = 90.25 mM
[A-] = 1.77(90.25) = 159.74 mM
The reducing agent in the reaction 2Li(s) + Fe(CH₃COO)₂(aq) → 2LiCH₃COO(aq) + Fe(s) is lithium (Li).
The general reaction is:
2Li(s) + Fe(CH₃COO)₂(aq) → 2LiCH₃COO(aq) + Fe(s) (1)
We can write the above reaction in <u>two reactions</u>, one for oxidation and the other for reduction:
Li⁰(s) → Li⁺(aq) + e⁻ (2)
Fe²⁺(aq) + 2e⁻ → Fe⁰(s) (3)
We can see that Li⁰ is oxidizing to Li⁺ (by <u>losing</u> one electron) in the lithium acetate (<em>reaction 2</em>) and that Fe²⁺ in iron(II) acetate is reducing to Fe⁰ (by <u>gaining</u> two <em>electrons</em>) (<em>reaction 3</em>).
We must remember that the reducing agent is the one that will be oxidized by <u>reducing another element</u> and that the oxidizing agent is the one that will be reduced by <u>oxidizing another species</u>.
In reaction (1), the<em> reducing agent</em> is <em>Li</em> (it is oxidizing to Li⁺), and the <em>oxidizing agent </em>is<em> Fe(CH₃COO)₂</em> (it is reducing to Fe⁰).
Therefore, the reducing agent in reaction (1) is lithium (Li).
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Concentration of unknown acid is 0.061 M
Given:
Concentration of NaOH = 0.125 M
Volume of NaOH = 24.68 mL
Volume of acid solution = 50.00 mL
To Find:
Concentration of the unknown acid
Solution: Concentration is the abundance of a constituent divided by the total volume of a mixture. The concentration of the solution tells you how much solute has been dissolved in the solvent
Here we will use the formula for concentration:
M1V1 = M2V2
0.125 x 24.68 = 50 x M2
M2 = 0.125 x 24.68 / 50
M2 = 0.061 M
Hence, the concentration of unknown acid is 0.061 M
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