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wel
3 years ago
7

Polly wants a white cracker

Chemistry
1 answer:
satela [25.4K]3 years ago
3 0
Me too I love crackers
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M = 163 m/z) is formed.
DanielleElmas [232]

Answer:

            As the molecular mass of given amine is 163 g/mol (a odd number) it means that this compound contains a odd number of Nitrogen atoms. We will first apply Rule of Thirteen to get the molecular formula.

Rule of Thirteen:

First divide the parent peak value by 13 as,

                = 163 ÷ 13

                = 12.53

Now, multiply 13 by 12,

                = 13 × 12 (here, 12 specifies number of carbon atoms)

                = 156

Now subtract 156 from 163,

                = 163 - 156

                = 7

Add 7 into 12,

                = 7 + 12

                = 19 (hydrogen atoms)

So, the rough formula we have is,

                                                       C₁₂H₁₉

Now, add one Nitrogen atom to above formula and subtract one Carbon and 2 Hydrogen atoms as these numbers are equal to atomic mass of Nitrogen atom as,

                C₁₂H₁₉   -------N-------->    C₁₁H₁₇N

Also, as shown in ¹³C-NMR there is one peak around 180 ppm and the peak at 1661 cm⁻¹ in IR spectrum is characteristic to carbonyl group hence, we will add one oxygen atom to the chemical formula accordingly. i.e.

                C₁₁H₁₇N   -------O-------->    C₁₀H₁₃NO

Molecular Formula: C₁₀H₁₃NO

Also,

In NMR the the four peaks around 120 ppm are assigned to a mono substituted benzene ring.

The absence of IR peak above 3200 cm⁻³ also confirms that the amine is tertiary in nature and there is no hydrogen attached to the nitrogen atom.

It can be observed that the peaks in upfield are duplicating. This can be due to the presence of rotamers of said compound.

The most plausible structure for given data is shown below, and the resonance structure along with rotamers are also shown.

6 0
3 years ago
The acid-dissociation constant for benzoic acid (C6H5COOH) is 6.3×10−5. Calculate the equilibrium concentration of H3O+ in the s
raketka [301]

Answer : The equilibrium concentration of H_3O^+ in the solution is, 2.1\times 10^{-3}M

Explanation :

The dissociation of acid reaction is:

                       C_6H_5COOH+H_2O\rightarrow H_3O^++C_6H_5COO^-

Initial conc.        c                                 0                0

At eqm.             c-x                                 x                x

Given:

c = 7.0\times 10^{-2}M

K_a=6.3\times 10^{-5}

The expression of dissociation constant of acid is:

K_a=\frac{[H_3O^+][C_6H_5COO^-]}{[C_6H_5COOH]}

K_a=\frac{(x)\times (x)}{(c-x)}

Now put all the given values in this expression, we get:

6.3\times 10^{-5}=\frac{(x)\times (x)}{[(7.0\times 10^{-2})-x]}

x=2.1\times 10^{-3}M

Thus, the equilibrium concentration of H_3O^+ in the solution is, 2.1\times 10^{-3}M

4 0
3 years ago
Solve the following division problem: (3.4 x 10^7)/(6.8 x 10^3) =
eduard

Answer:

5000

Explanation:

8 0
3 years ago
A cast fossil is formed when
Liono4ka [1.6K]
The answer is D)
<span>when the remains of a living thing are preserved and turned into rock </span>
8 0
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How can flood water affect the public drinking water supply?
storchak [24]
Flood water will ruin the clean water. This will cause the water to be undrinkable. Flood water will get into homes and ruin roads. Even though it may seem like it is doing a good thing by adding more water, the water is not filtered and clean for drinking.
8 0
3 years ago
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