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son4ous [18]
3 years ago
6

A scientist measures the standard enthalpy change for the following reaction to be 67.9 kJ:

Chemistry
1 answer:
bekas [8.4K]3 years ago
3 0

Answer: The standard enthalpy of formation  of H_2O(g) is  -252.1 kJ/mol.

Explanation:

The balanced chemical reaction is,

Fe_2O_3(s)+3H_2(g)\rightarrow 2Fe(s)+3H_2O(g)

The expression for enthalpy change is,

\Delta H=[n\times H_f_{products}]-[n\times H_f_{reactantss}]

Putting the values we get :

\Delta H=[2\times H_f{Fe}+3\times H_f{H_2O}]-[1\times H_f{Fe_2O_3}+3\times H_f{H_2}]

67.9kJ=[(2\times 0)+(3\times H_f{H_2O})]-[(1\times -824.2kJ/mol)+3\times 0kJ/mol)]

H_f{H_2O}=-252.1kJ/mol

Thus standard enthalpy of formation  of H_2O(g) is  -252.1 kJ/mol.

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Calculate the standard reaction enthalpy for the reaction NO2(g) → NO(g) + O(g) given +142.7 kJ/mol for the standard enthalpy of
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Answer:

The standard reaction enthalpy for the given reaction is 235.15 kJ/mol.

Explanation:

O_2(g) \rightarrow \frac{2}{3}O_3(g),\Delta H^o_{1}=142.7 kJ/mol..[1]

O_2(g) \rightarrow 2 O(g),\Delta H^o_{2}=498.4 kJ/mol..[2]

NO(g) + O_3(g)\rightarrow NO_2(g) + O_2(g) ,\Delta H^o_{3} = -200 kJ/mol..[3]

NO_2(g)\rightarrow NO(g) + O(g),\Delta H^o_{4}=?..[4]

Using Hess's law:

Hess’s law of constant heat summation states that the amount of heat absorbed or evolved in a given chemical equation remains the same whether the process occurs in one step or several steps.

2 × [4] = [2]- (3 ) × [1] - (2) × [3]

2\times \Delta H^o_{4}=\Delta H^o_{2} -3\times \Delta H^o_{1}-2\times \Delta H^o_{3}

2\times \Delta H^o_{4}=498.4 kJ/mol-3\times 142.7 kJ/mol-2\times -200 kJ/mol

2\times \Delta H^o_{4}=470.3 kJ/mol

\Delta H^o_{4}=\frac{470.3 kJ/mol}{2}=235.15 kJ/mol

The standard reaction enthalpy for the given reaction is 235.15 kJ/mol.

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