The cotangent function is defined as the ratio between cosine and sine of a given angle, i.e.
Since you can't have zero at the denominator, the cotangent function is not defined when the sine is zero.
Let's look at your option:
, so the cotangent is defined here
, so the cotangent is not defined here
, so the cotangent is defined here
, so the cotangent is defined here