Answer:
k₂ = 4.06 x 10⁻² s⁻¹.
Explanation:
- From Arrhenius law: <em>K = Ae(-Ea/RT)</em>
where, K is the rate constant of the reaction.
A is the Arrhenius factor.
Ea is the activation energy.
R is the general gas constant.
T is the temperature.
- At different temperatures:
<em>ln(k₂/k₁) = Ea/R [(T₂-T₁)/(T₁T₂)]</em>
k₁ = 5.8 × 10⁻³ s⁻¹, k₂ = ??? , Ea = 33600 J/mol, R = 8.314 J/mol.K, T₁ = 298.0 K, T₂ = 348.0 K.
- ln(k₂/5.8 × 10⁻³ s⁻¹) = (33600 J/mol / 8.314 J/mol.K) [(348.0 K - 298.0 K) / (298.0 K x 348.0 K)] = (4041.37) (4.82 x 10⁻⁴) = 1.9479.
- Taking exponential of both sides:
(k₂/5.8 × 10⁻³ s⁻¹) = 7.014.
∴ k₂ = 4.06 x 10⁻² s⁻¹.
<span>C. New substances are always produced in chemical changes, which is not the case with physical changes. For example, when you cut wood into smaller pieces you still have wood in the end. But, with a chemical change you change the substance's whole composition. For example when you add two hydrogen's to one oxygen you have water and it can't break down from that. </span><span />
2,8,1
It's in group 1, so its outershell only has 1 electron, and the other shells are completely filled, so 2 then 8. :)
Facilitated diffusion is your answer
Here's my best guess
the volume of the unit cell is (385*10^-12)^3=5.7066*10^-29 m^3
multiply by density to get mass
mass = (7 g/cm^3)*(100^3 cm^3 / 1^3 m^3) * 5.7066*10^-29 m^3= 3.99466*10^-22 g
covert to moles
3.99466*10^-22 g * 1 mol / 239.82 g = 1.6657 *10^-24 mol
convert to number of units
1.6657 *10^-24 mol * 6.23*10^23 units/mol = 1.04
385 pm = 3.85*10^(-8) cm
The volume of the unit cell is the cube of that, which is 5.71*10^(-23) cm^3. Since the ratio of mass to volume (i.e. the density) must be the same no matter what amount of TlCl you have, you can say:
7 = x/(5.71*10^(-23)), where x is the mass of the unit cell. Solving for x, you get 4*10^(-22) g.
The mass of a molecule of TlCl is 240 amu, which in grams is 4*10^(-22) g. The mass of the unit cell and the mass of a molecule of TlCl is the same. Therefore there is one formula unit of TlCl per unit cell.
