There are a couple of ways in which you can express the concentration of a solution, and here they are: gram per liter (g/L), molarity (M), parts per million (ppm.), and percents (%).
As you can see, only M appears in your answers, which means that the correct option should be (2) 3.5 M.
Can you take picture of the whole question? I can’t see.
Answer is: elements are always combined in the same proportion by mass.
Law of multiple proportions or Dalton's Law said that the ratios of the masses of the second element which combine with a fixed mass of the first element will be ratios of small whole numbers.
For example, nitrogen(I) oxide N₂O; m(N) : m(O) = 2·14 : 16 = 7 : 4.
Another example, water (H₂O) is made of two hydrogen atoms and one oxygen atom:
m(H) : m(O) = 2·1 : 16 = 1: 8.
Inert properties
<span>Nitrogen is used to protect steel from water because it has inert properties that make it a good blanketing gas.</span>